DICP OpenIR
Subject Area物理化学
Capillary supported ultrathin homogeneous silicalite-poly(dimethylsiloxane) nanocomposite membrane for bio-butanol recovery
Liu, Xinlei1,2; Li, Yanshuo1; Liu, Yi1,2; Zhu, Guangqi1; Liu, Jie1; Yang, Weishen1; Yang WS(杨维慎)
KeywordSilicalite-pdms Nanocomposite Membrane Capillary Support Pervaporation Butanol
Source PublicationJOURNAL OF MEMBRANE SCIENCE
2011-03-01
ISSN待补充
DOI10.1016/j.memsci.2010.11.074
Volume369Issue:1-2Pages:228-232
Indexed BySCI
SubtypeArticle
Department5
Funding Project504
Contribution Rank1,1
WOS HeadingsScience & Technology ; Technology ; Physical Sciences
WOS SubjectEngineering, Chemical ; Polymer Science
WOS Research AreaEngineering ; Polymer Science
WOS KeywordDILUTE AQUEOUS-SOLUTIONS ; ABE FERMENTATION BROTH ; PERVAPORATIVE RECOVERY ; COMPOSITE MEMBRANES ; PDMS MEMBRANES ; GAS SEPARATION ; SILICALITE ; ZEOLITE ; PERFORMANCE ; 1-BUTANOL
AbstractCapillary supported ultrathin homogeneous silicalite-poly(dimethylsiloxane) nanocomposite membrane for bio-butanol recovery; An ultrathin (300 nm) homogeneous silicalite-poly(dimethylsiloxane) (PDMS) nanocomposite membrane was fabricated on capillary support by a "Packing-filling" method. Firstly, silicalite-1 nano-crystals were deposited onto a porous alumina capillary support using dip-coating technique (packing); secondly, the interspaces among the nano-crystals were filled with PDMS phase (filling). No voids between nano-crystals and PDMS phase were observed by scanning electron microscopy (SEM), suggesting good zeolite-polymer adhesion. The membrane possesses very high flux (5.0-11.2 kg m(-2) h(-1)) and good separation factor (25.0-41.6) for the pervaporative recovery of iso-butanol from aqueous solution (0.2-3 wt.%) at 80 degrees C. Such properties offer great potential towards applications in fermentation-pervaporation coupled processes. The effects of feed temperature and concentration on the pervaporation performance of this nanocomposite membrane were investigated. (C) 2010 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000287832200027
Citation statistics
Cited Times:49[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115176
Collection中国科学院大连化学物理研究所
Corresponding AuthorYang WS(杨维慎)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liu, Xinlei,Li, Yanshuo,Liu, Yi,et al. Capillary supported ultrathin homogeneous silicalite-poly(dimethylsiloxane) nanocomposite membrane for bio-butanol recovery[J]. JOURNAL OF MEMBRANE SCIENCE,2011,369(1-2):228-232.
APA Liu, Xinlei.,Li, Yanshuo.,Liu, Yi.,Zhu, Guangqi.,Liu, Jie.,...&杨维慎.(2011).Capillary supported ultrathin homogeneous silicalite-poly(dimethylsiloxane) nanocomposite membrane for bio-butanol recovery.JOURNAL OF MEMBRANE SCIENCE,369(1-2),228-232.
MLA Liu, Xinlei,et al."Capillary supported ultrathin homogeneous silicalite-poly(dimethylsiloxane) nanocomposite membrane for bio-butanol recovery".JOURNAL OF MEMBRANE SCIENCE 369.1-2(2011):228-232.
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