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学科主题: 物理化学
题名: Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes
作者: Zhao, Guang-Jiu1;  Yu, Fabiao1;  Zhang, Ming-Xing1;  Northrop, Brian H.2;  Yang, Haibo2;  Han, Ke-Li1;  Stang, Peter J.2
通讯作者: 韩克利
刊名: JOURNAL OF PHYSICAL CHEMISTRY A
发表日期: 2011-06-23
DOI: 10.1021/jp202825q
卷: 115, 期:24, 页:6390-6393
收录类别: SCI
文章类型: Article
部门归属: 11
项目归属: 1101
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
摘要: Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes
研究领域[WOS]: Chemistry ;  Physics
英文摘要: An investigation of a series of platinum-containing organometallic complexes for the study of fluorescence phenomena in organometallic chromophores controlled by the intrarnolecular charge transfer (ICT) is presented in this work. We report steady-state and time-resolved spectroscopic experiments as well as quantum chemistry calculations to investigate the substituent effects on the ICT and fluorescence emission. We demonstrate that the fluorescence maximum and lifetimes greatly depend on different substituents and the presence of bimetallic platinum donor. This work paves the way for an understanding of the fluorescence phenomena controlled by molecular ICT characters of these kinds of platinum-containing organometallic complexes.
关键词[WOS]: SUPRAMOLECULAR RECTANGLE ;  TERPYRIDYL COMPLEXES ;  COORDINATION CAGES ;  DIMER COMPLEX ;  PHOTOCHEMISTRY ;  SYMMETRY ;  SYSTEMS ;  INTERMEDIATE ;  SPECTROSCOPY ;  PHOTOPHYSICS
语种: 英语
WOS记录号: WOS:000291709400010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115233
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

Recommended Citation:
Zhao, Guang-Jiu,Yu, Fabiao,Zhang, Ming-Xing,et al. Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2011,115(24):6390-6393.
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