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学科主题物理化学
Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes
Zhao, Guang-Jiu1; Yu, Fabiao1; Zhang, Ming-Xing1; Northrop, Brian H.2; Yang, Haibo2; Han, Ke-Li1; Stang, Peter J.2; Han KL(韩克利)
刊名JOURNAL OF PHYSICAL CHEMISTRY A
2011-06-23
ISSN待补充
DOI10.1021/jp202825q
115期:24页:6390-6393
收录类别SCI
文章类型Article
部门归属11
项目归属1101
产权排名1,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]SUPRAMOLECULAR RECTANGLE ; TERPYRIDYL COMPLEXES ; COORDINATION CAGES ; DIMER COMPLEX ; PHOTOCHEMISTRY ; SYMMETRY ; SYSTEMS ; INTERMEDIATE ; SPECTROSCOPY ; PHOTOPHYSICS
英文摘要Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes; An investigation of a series of platinum-containing organometallic complexes for the study of fluorescence phenomena in organometallic chromophores controlled by the intrarnolecular charge transfer (ICT) is presented in this work. We report steady-state and time-resolved spectroscopic experiments as well as quantum chemistry calculations to investigate the substituent effects on the ICT and fluorescence emission. We demonstrate that the fluorescence maximum and lifetimes greatly depend on different substituents and the presence of bimetallic platinum donor. This work paves the way for an understanding of the fluorescence phenomena controlled by molecular ICT characters of these kinds of platinum-containing organometallic complexes.
语种英语
WOS记录号WOS:000291709400010
引用统计
被引频次:67[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115233
专题中国科学院大连化学物理研究所
通讯作者Han KL(韩克利)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
推荐引用方式
GB/T 7714
Zhao, Guang-Jiu,Yu, Fabiao,Zhang, Ming-Xing,et al. Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2011,115(24):6390-6393.
APA Zhao, Guang-Jiu.,Yu, Fabiao.,Zhang, Ming-Xing.,Northrop, Brian H..,Yang, Haibo.,...&韩克利.(2011).Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes.JOURNAL OF PHYSICAL CHEMISTRY A,115(24),6390-6393.
MLA Zhao, Guang-Jiu,et al."Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes".JOURNAL OF PHYSICAL CHEMISTRY A 115.24(2011):6390-6393.
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