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学科主题: 物理化学
题名: Acid controlled diastereoselectivity in asymmetric aldol reaction of cycloketones with aldehydes using enamine-based organocatalysts
作者: Gao, Jinsuo1, 2;  Bai, Shiyang1;  Gao, Qiang1;  Liu, Yan1;  Yang, Qihua1
通讯作者: 杨启华 ;  刘
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2011
DOI: 10.1039/c0cc05224h
卷: 47, 期:23, 页:6716-6718
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 5
项目归属: 506
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
摘要: Acid controlled diastereoselectivity in asymmetric aldol reaction of cycloketones with aldehydes using enamine-based organocatalysts
研究领域[WOS]: Chemistry
英文摘要: The example of syn-aldol reaction of cyclohexanone to aldehyde was demonstrated based on chiral diamine organocatalysts and it was realized either by increasing the molecular size of acid additives or by introducing a hydrogen-bond donor into acid additives.
关键词[WOS]: MANNICH-TYPE REACTIONS ;  DIELS-ALDER REACTIONS ;  ALIPHATIC-KETONES ;  ANTI-MANNICH ;  CATALYSIS ;  WATER ;  DIHYDROXYACETONE ;  STEREOCENTERS ;  PROLINE ;  MICHAEL
语种: 英语
WOS记录号: WOS:000291113000061
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115275
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Key Lab Ind Ecol & Environm Engn, Minist Educ, Sch Environm Sci & Technol, Dalian 116024, Peoples R China

Recommended Citation:
Gao, Jinsuo,Bai, Shiyang,Gao, Qiang,et al. Acid controlled diastereoselectivity in asymmetric aldol reaction of cycloketones with aldehydes using enamine-based organocatalysts[J]. CHEMICAL COMMUNICATIONS,2011,47(23):6716-6718.
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