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学科主题: 物理化学
题名: Synthesis and enantioselective hydrogenation of seven-membered cyclic imines: substituted dibenzo[b,f][1,4]oxazepines
作者: Gao, Kai1;  Yu, Chang-Bin1;  Li, Wei2;  Zhou, Yong-Gui1;  Zhang, Xumu2
通讯作者: 周永贵 ;  张绪穆
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2011
DOI: 10.1039/c1cc12263k
卷: 47, 期:27, 页:7845-7847
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 201
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
摘要: Synthesis and enantioselective hydrogenation of seven-membered cyclic imines: substituted dibenzo[b,f][1,4]oxazepines
研究领域[WOS]: Chemistry
英文摘要: Highly enantioselective hydrogenation of seven-membered cyclic imines, substituted dibenzo[b,f][1,4]oxazepines, was achieved, with up to 94% ee, by using the [Ir(COD)Cl](2)/(S)-Xyl-C(3)(*)-TunePhos complex as the catalyst in the presence of morpholine-HCl.
关键词[WOS]: CATALYZED ASYMMETRIC HYDROGENATION ;  HIV-1 REVERSE-TRANSCRIPTASE ;  N-ARYL IMINES ;  HETEROAROMATIC-COMPOUNDS ;  QUINOLINE DERIVATIVES ;  IRIDIUM COMPLEXES ;  ACYCLIC IMINES ;  LIGANDS ;  INHIBITORS ;  KETIMINES
语种: 英语
WOS记录号: WOS:000292113700085
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115411
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Rutgers State Univ, Dept Chem, Piscataway, NJ 08854 USA

Recommended Citation:
Gao, Kai,Yu, Chang-Bin,Li, Wei,et al. Synthesis and enantioselective hydrogenation of seven-membered cyclic imines: substituted dibenzo[b,f][1,4]oxazepines[J]. CHEMICAL COMMUNICATIONS,2011,47(27):7845-7847.
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