DICP OpenIR
学科主题物理化学
Synthesis of Electronically Deficient Atropisomeric Bisphosphine Ligands and Their Application in Asymmetric Hydrogenation of Quinolines
Zhang, De-Yang1,2; Wang, Duo-Sheng2; Wang, Min-Can1; Yu, Chang-Bin2; Gao, Kai2; Zhou, Yong-Gui2; Wang MC(王敏灿); Zhou YG(周永贵)
关键词Iridium Asymmetric Hydrogenation Electron-deficient Ligands Quinolines
刊名SYNTHESIS-STUTTGART
2011-09-01
ISSN待补充
DOI10.1055/s-0030-1260129
17期:17页:2796-2802
收录类别SCI ; IC ; CCR
文章类型Article
部门归属2
项目归属201
产权排名2,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]HIGHLY ENANTIOSELECTIVE HYDROGENATION ; IRIDIUM-CATALYZED HYDROGENATION ; HETEROAROMATIC-COMPOUNDS ; PYRIDINE-DERIVATIVES ; COMPLEXES ; INDOLES ; EFFICIENT ; QUINOXALINES ; VERSATILE ; TETRAHYDROQUINOXALINES
英文摘要Synthesis of Electronically Deficient Atropisomeric Bisphosphine Ligands and Their Application in Asymmetric Hydrogenation of Quinolines; A series of electronically deficient atropisomeric bisphosphine ligands have been synthesized from (S)-MeO-BiPhep. The introduction of electron-withdrawing groups in the ligands had a dramatic influence on both the enantioselectivity and the activity of catalyst. The iridium complex of the MeO-BiPhep-based ligand bearing a trifluoromethanesulfonyl group was successfully applied in the asymmetric hydrogenation of quinolines with ee values of up to 95% and turnover numbers (TON) of up to 14,600.
语种英语
WOS记录号WOS:000294158700015
引用统计
被引频次:23[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115412
专题中国科学院大连化学物理研究所
通讯作者Wang MC(王敏灿); Zhou YG(周永贵)
作者单位1.Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zhang, De-Yang,Wang, Duo-Sheng,Wang, Min-Can,et al. Synthesis of Electronically Deficient Atropisomeric Bisphosphine Ligands and Their Application in Asymmetric Hydrogenation of Quinolines[J]. SYNTHESIS-STUTTGART,2011,17(17):2796-2802.
APA Zhang, De-Yang.,Wang, Duo-Sheng.,Wang, Min-Can.,Yu, Chang-Bin.,Gao, Kai.,...&周永贵.(2011).Synthesis of Electronically Deficient Atropisomeric Bisphosphine Ligands and Their Application in Asymmetric Hydrogenation of Quinolines.SYNTHESIS-STUTTGART,17(17),2796-2802.
MLA Zhang, De-Yang,et al."Synthesis of Electronically Deficient Atropisomeric Bisphosphine Ligands and Their Application in Asymmetric Hydrogenation of Quinolines".SYNTHESIS-STUTTGART 17.17(2011):2796-2802.
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