DICP OpenIR
学科主题物理化学
Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones
Chen, Qing-An; Chen, Mu-Wang; Yu, Chang-Bin; Shi, Lei; Wang, Duo-Sheng; Yang, Yan; Zhou, Yong-Gui; Zhou YG(周永贵)
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2011-10-19
ISSN待补充
DOI10.1021/ja208073w
133期:41页:16432-16435
收录类别SCI
文章类型Article
部门归属2
项目归属201
产权排名1,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ENANTIOSELECTIVE TRANSFER HYDROGENATION ; BRONSTED ACID CATALYSIS ; CHIRAL PHOSPHORIC-ACIDS ; ORGANOCATALYTIC TRANSFER HYDROGENATION ; ALPHA-IMINO ESTERS ; BOND-FORMING REACTIONS ; N-H KETIMINES ; REDUCTIVE AMINATION ; TRANSITION-METAL ; ALPHA,BETA-UNSATURATED ALDEHYDES
英文摘要Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones; A catalytic amount of Hantzsch ester that could be regenerated in situ by Ru complexes under hydrogen gas has been employed in the biomimetic asymmetric hydrogenation of benzoxazinones with up to 99% ee in the presence of chiral phosphoric acid. The use of hydrogen gas as a reductant for the regeneration of Hantzsch esters makes this hydrogenation an ideal atom economic process.
语种英语
WOS记录号WOS:000295997500030
引用统计
被引频次:110[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115413
专题中国科学院大连化学物理研究所
通讯作者Zhou YG(周永贵)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Chen, Qing-An,Chen, Mu-Wang,Yu, Chang-Bin,et al. Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(41):16432-16435.
APA Chen, Qing-An.,Chen, Mu-Wang.,Yu, Chang-Bin.,Shi, Lei.,Wang, Duo-Sheng.,...&周永贵.(2011).Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(41),16432-16435.
MLA Chen, Qing-An,et al."Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.41(2011):16432-16435.
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