DICP OpenIR
Subject Area物理化学
Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones
Chen, Qing-An; Chen, Mu-Wang; Yu, Chang-Bin; Shi, Lei; Wang, Duo-Sheng; Yang, Yan; Zhou, Yong-Gui; Zhou YG(周永贵)
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2011-10-19
ISSN待补充
DOI10.1021/ja208073w
Volume133Issue:41Pages:16432-16435
Indexed BySCI
SubtypeArticle
Department2
Funding Project201
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordENANTIOSELECTIVE TRANSFER HYDROGENATION ; BRONSTED ACID CATALYSIS ; CHIRAL PHOSPHORIC-ACIDS ; ORGANOCATALYTIC TRANSFER HYDROGENATION ; ALPHA-IMINO ESTERS ; BOND-FORMING REACTIONS ; N-H KETIMINES ; REDUCTIVE AMINATION ; TRANSITION-METAL ; ALPHA,BETA-UNSATURATED ALDEHYDES
AbstractBiomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones; A catalytic amount of Hantzsch ester that could be regenerated in situ by Ru complexes under hydrogen gas has been employed in the biomimetic asymmetric hydrogenation of benzoxazinones with up to 99% ee in the presence of chiral phosphoric acid. The use of hydrogen gas as a reductant for the regeneration of Hantzsch esters makes this hydrogenation an ideal atom economic process.
Language英语
WOS IDWOS:000295997500030
Citation statistics
Cited Times:114[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115413
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhou YG(周永贵)
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Chen, Qing-An,Chen, Mu-Wang,Yu, Chang-Bin,et al. Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(41):16432-16435.
APA Chen, Qing-An.,Chen, Mu-Wang.,Yu, Chang-Bin.,Shi, Lei.,Wang, Duo-Sheng.,...&周永贵.(2011).Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(41),16432-16435.
MLA Chen, Qing-An,et al."Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.41(2011):16432-16435.
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