DICP OpenIR
学科主题物理化学
Improving Effects of LiH and Co-Catalyst on the Dehydrogenation of Li4BN3H10
Zheng, Xueli1,2; Xiong, Zhitao2; Lim, Yonghao3; Wu, Guotao2; Chen, Ping2,3; Chen, Hua1; Xiong ZT(熊智涛)
刊名JOURNAL OF PHYSICAL CHEMISTRY C
2011-05-05
ISSN待补充
DOI10.1021/jp2007182
115期:17页:8840-8844
收录类别SCI
文章类型Article
部门归属19
项目归属1901
产权排名2,1
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]N-H SYSTEM ; REVERSIBLE HYDROGEN STORAGE ; CRYSTAL-STRUCTURE ; LITHIUM AMIDE ; DESORPTION ; RELEASE ; HYDRIDE ; COMPLEX ; LIBH4 ; LIB0.33N0.67H2.67
英文摘要Improving Effects of LiH and Co-Catalyst on the Dehydrogenation of Li4BN3H10; Improving effects of LiH and Co-catalyst on the dehydrogenation of Li4BN3H10 were investigated in this work. It was found that 9.6 wt % or 5 equiv. moles of H-2 can be evolved from the promoted sample at 250 degrees C, which is 110 degrees C lower than that of pristine Li4BN3H10. More importantly, NH3 emission is depressed dramatically, with its concentration in hydrogen decreasing from 12 mol % to 0.008 mol % (or 80 ppm). Melting of Li4BN3H10 is essential for one unit of LiNH2 fleeing from the structure and interacting with LiH to evolve 1 equiv. mole of H-2, in the meantime, Co-catalyst takes effect on the dissociation of remaining Li3BN2H8, resulting in the evolution of another 4 equiv. moles of H-2 at temperatures close to that of LiNH2-LiH.
语种英语
WOS记录号WOS:000289824200047
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115415
专题中国科学院大连化学物理研究所
通讯作者Xiong ZT(熊智涛)
作者单位1.Sichuan Univ, Key Lab Green Chem & Technol, Inst Homogeneous Catalysis, Minist Educ,Coll Chem, Chengdu 610064, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
推荐引用方式
GB/T 7714
Zheng, Xueli,Xiong, Zhitao,Lim, Yonghao,et al. Improving Effects of LiH and Co-Catalyst on the Dehydrogenation of Li4BN3H10[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2011,115(17):8840-8844.
APA Zheng, Xueli.,Xiong, Zhitao.,Lim, Yonghao.,Wu, Guotao.,Chen, Ping.,...&熊智涛.(2011).Improving Effects of LiH and Co-Catalyst on the Dehydrogenation of Li4BN3H10.JOURNAL OF PHYSICAL CHEMISTRY C,115(17),8840-8844.
MLA Zheng, Xueli,et al."Improving Effects of LiH and Co-Catalyst on the Dehydrogenation of Li4BN3H10".JOURNAL OF PHYSICAL CHEMISTRY C 115.17(2011):8840-8844.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2011gYHibQhn72.pdf(740KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zheng, Xueli]的文章
[Xiong, Zhitao]的文章
[Lim, Yonghao]的文章
百度学术
百度学术中相似的文章
[Zheng, Xueli]的文章
[Xiong, Zhitao]的文章
[Lim, Yonghao]的文章
必应学术
必应学术中相似的文章
[Zheng, Xueli]的文章
[Xiong, Zhitao]的文章
[Lim, Yonghao]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。