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学科主题: 物理化学
题名: Conversion of biomass into 5-hydroxymethylfurfural using solid acid catalyst
作者: Yang, Fengli1, 2;  Liu, Qishun1;  Bai, Xuefang1;  Du, Yuguang1
通讯作者: 杜昱光
关键词: Biomass ;  Dehydration ;  5-Hydroxymethylfurfural (HMF) ;  Niobic compound
刊名: BIORESOURCE TECHNOLOGY
发表日期: 2011-02-01
DOI: 10.1016/j.biortech.2010.10.023
卷: 102, 期:3, 页:3424-3429
收录类别: SCI
文章类型: Article
部门归属: 18
项目归属: 1805
产权排名: 1,1
WOS标题词: Science & Technology ;  Life Sciences & Biomedicine ;  Technology
类目[WOS]: Agricultural Engineering ;  Biotechnology & Applied Microbiology ;  Energy & Fuels
摘要: Conversion of biomass into 5-hydroxymethylfurfural using solid acid catalyst
研究领域[WOS]: Agriculture ;  Biotechnology & Applied Microbiology ;  Energy & Fuels
英文摘要: 5-Hydroxymethylfurfural (HMF) was produced from monosaccharide (fructose and glucose), polysaccharide (inulin) and the Jerusalem artichoke juice by a simple one-pot reaction including hydrolysis and dehydration using solid acid under mild condition. Hydrated niobium pentoxide (Nb(2)O(5)center dot nH(2)O(2)) after pre-treatment showed high catalytic activities for dehydration of mono- and polysaccharide to HMF at 433 K in water-2-butanol (2:3 v/v) biphasic system, giving high HMF yield of 89% and 54% from fructose and inulin, respectively. The HMF yield was up to 74% and 65% when inulin and Jerusalem artichoke juice were hydrolyzed by exoinulinase. The solid acid made the process environment-friendly and energy-efficient to convert carbohydrates into bio-fuels and platform chemicals. (C) 2010 Elsevier Ltd. All rights reserved.
关键词[WOS]: NIOBIC ACID ;  FRUCTOSE DEHYDRATION ;  PHOSPHATE CATALYSTS ;  JERUSALEM-ARTICHOKE ;  ETHANOL-PRODUCTION ;  PHOSPHORIC-ACID ;  LIQUID-PHASE ;  WATER ;  FUELS ;  5-HYDROXYMETHYL-2-FURALDEHYDE
语种: 英语
WOS记录号: WOS:000286904500181
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115514
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Liaoning Prov Key Lab Carbohydrates, Nat Prod & Glycobiotechnol Res Grp,CAS, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Yang, Fengli,Liu, Qishun,Bai, Xuefang,et al. Conversion of biomass into 5-hydroxymethylfurfural using solid acid catalyst[J]. BIORESOURCE TECHNOLOGY,2011,102(3):3424-3429.
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