DICP OpenIR
Subject Area物理化学
Esterification of glycerol with acetic acid using double SO3H-functionalized ionic liquids as recoverable catalysts
Liu, Xiumei1; Ma, Huiyuan2; Wu, Yue2; Wang, Chang1; Yang, Miao1; Yan, Peifang1; Welz-Biermann, Urs1; Liu XM(刘秀梅); UrsWelz-Biermann
Source PublicationGREEN CHEMISTRY
2011
ISSN待补充
DOI10.1039/c0gc00732c
Volume13Issue:3Pages:697-701
Indexed BySCI
SubtypeArticle
Department2
Funding Project207
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordFISCHER ESTERIFICATION ; ACETYLATION ; SILICA
AbstractEsterification of glycerol with acetic acid using double SO3H-functionalized ionic liquids as recoverable catalysts; Esterification of glycerol with acetic acid was studied using a series of Bronsted acidic ionic liquids as catalysts. The results indicate that double SO3H-functionalized ionic liquids show high catalytic activity and fair reusability even at very low catalyst loadings, while the conventional non-functionalized ionic liquids show poor activity. The Bronsted acidity-catalytic activity relationships were also investigated and the results showed that the sequence of the catalytic activity observed in the transformation was in good agreement with the Bronsted acidity order determined by the Hammett method.
Language英语
WOS IDWOS:000288126300032
Citation statistics
Cited Times:64[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115559
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiu XM(刘秀梅); UrsWelz-Biermann
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China
2.Liaoning Normal Univ, Sch Chem & Chem Engn, Dalian 116012, Peoples R China
Recommended Citation
GB/T 7714
Liu, Xiumei,Ma, Huiyuan,Wu, Yue,et al. Esterification of glycerol with acetic acid using double SO3H-functionalized ionic liquids as recoverable catalysts[J]. GREEN CHEMISTRY,2011,13(3):697-701.
APA Liu, Xiumei.,Ma, Huiyuan.,Wu, Yue.,Wang, Chang.,Yang, Miao.,...&UrsWelz-Biermann.(2011).Esterification of glycerol with acetic acid using double SO3H-functionalized ionic liquids as recoverable catalysts.GREEN CHEMISTRY,13(3),697-701.
MLA Liu, Xiumei,et al."Esterification of glycerol with acetic acid using double SO3H-functionalized ionic liquids as recoverable catalysts".GREEN CHEMISTRY 13.3(2011):697-701.
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