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学科主题: 物理化学
题名: Esterification of glycerol with acetic acid using double SO3H-functionalized ionic liquids as recoverable catalysts
作者: Liu, Xiumei1;  Ma, Huiyuan2;  Wu, Yue2;  Wang, Chang1;  Yang, Miao1;  Yan, Peifang1;  Welz-Biermann, Urs1
通讯作者: 刘秀梅 ;  UrsWelz-Biermann
刊名: GREEN CHEMISTRY
发表日期: 2011
DOI: 10.1039/c0gc00732c
卷: 13, 期:3, 页:697-701
收录类别: SCI
文章类型: Article
部门归属: 2
项目归属: 207
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
摘要: Esterification of glycerol with acetic acid using double SO3H-functionalized ionic liquids as recoverable catalysts
研究领域[WOS]: Chemistry
英文摘要: Esterification of glycerol with acetic acid was studied using a series of Bronsted acidic ionic liquids as catalysts. The results indicate that double SO3H-functionalized ionic liquids show high catalytic activity and fair reusability even at very low catalyst loadings, while the conventional non-functionalized ionic liquids show poor activity. The Bronsted acidity-catalytic activity relationships were also investigated and the results showed that the sequence of the catalytic activity observed in the transformation was in good agreement with the Bronsted acidity order determined by the Hammett method.
关键词[WOS]: FISCHER ESTERIFICATION ;  ACETYLATION ;  SILICA
语种: 英语
WOS记录号: WOS:000288126300032
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115559
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China
2.Liaoning Normal Univ, Sch Chem & Chem Engn, Dalian 116012, Peoples R China

Recommended Citation:
Liu, Xiumei,Ma, Huiyuan,Wu, Yue,et al. Esterification of glycerol with acetic acid using double SO3H-functionalized ionic liquids as recoverable catalysts[J]. GREEN CHEMISTRY,2011,13(3):697-701.
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