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学科主题: 物理化学
题名: Surface Tension and Density of Ionic Liquid n-Butylpyridinium Heptachlorodialuminate
作者: Tong, Jing1;  Liu, Qing-Shan2;  Wang, Pan-Pan1;  Welz-Biermann, Urs2;  Yang, Jia-Zhen1
通讯作者: JingTong
刊名: JOURNAL OF CHEMICAL AND ENGINEERING DATA
发表日期: 2011-10-01
DOI: 10.1021/je200471w
卷: 56, 期:10, 页:3722-3724
收录类别: SCI
文章类型: Article
部门归属: 2
项目归属: 207
产权排名: 2,2
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Engineering, Chemical
摘要: Surface Tension and Density of Ionic Liquid n-Butylpyridinium Heptachlorodialuminate
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: An ionic liquid (IL), [C(4)Py][Al(2)Cl(7)] (n-butylpyridinium heptachlorodialuminate), was prepared, and its density and surface tension were measured under dry argon in the temperature range from (298.15 to 333.15) K. The experimental data showed that the Eotvos equation was applicable to the IL and the experimental parachor value was larger than that calculated from neutral parachor contribution which did not consider the Coulomb interaction in IL. In terms of Glasser's theory, the molar entropy, S(0), and the lattice energy, U(POT) were estimated. Using Kabo's method the molar enthalpy of vaporization Delta(8)(1)H(m)(0) (298 K) and using the interstice model the thermal expansion coefficient, alpha, for [C(4)Py][Al(2)Cl(7)] were predicted, respectively.
关键词[WOS]: PHYSICOCHEMICAL PROPERTIES ;  PHYSICAL-PROPERTIES ;  ALUMINUM-CHLORIDE ;  TEMPERATURE ;  SOLVENTS ;  SYSTEM
语种: 英语
WOS记录号: WOS:000295700500002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115561
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Univ, Key Lab Green Synth & Preparat Chem Adv Mat, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China

Recommended Citation:
Tong, Jing,Liu, Qing-Shan,Wang, Pan-Pan,et al. Surface Tension and Density of Ionic Liquid n-Butylpyridinium Heptachlorodialuminate[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2011,56(10):3722-3724.
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