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学科主题物理化学
An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures
Zhang, Zehui1,3,4; Liu, Wujun1; Xie, Haibo1,2; Zhao, Zongbao K.1,2; Xie HB(谢海波); Zhao ZB(赵宗保)
关键词Side Reaction Hmf Ionic Liquids 1-butyl-2-(5 '-methyl-2 '-furoyl)Imidazole
刊名MOLECULES
2011-10-01
ISSN1420-3049
DOI10.3390/molecules16108463
16期:10页:8463-8474
收录类别SCI
文章类型Article
部门归属18
项目归属1816
产权排名1,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]PHYSICAL-PROPERTIES ; SOLVENTS ; SOLUBILITY ; CONVERSION ; CATALYSIS ; CHEMISTRY ; SALTS
英文摘要An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures; A new compound was detected during the production of 5-hydroxymethylfurfural (HMF) from glucose and cellulose in the ionic liquid 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) at high temperatures. Further experiments found that it was derived from the reaction of HMF with [Bmim]Cl. The structure of new compound was established as 1-butyl-2-(5'-methyl-2'-furoyl) imidazole (BMI) based on nuclear magnetic resonance and mass spectrometry analysis, and a possible mechanism for its formation was proposed. Reactions of HMF with other imidazolium-based ionic liquids were performed to check the formation of BMI. Our results provided new insights in terms of side reactions between HMF and imidazolium-based ionic liquids, which should be valuable for designing better processes for the production of furans using biomass and related materials.
语种英语
WOS记录号WOS:000296973000024
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115575
专题中国科学院大连化学物理研究所
通讯作者Xie HB(谢海波); Zhao ZB(赵宗保)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China
4.S Cent Univ Nationalities, Minist Educ, Coll Chem & Mat Sci, Wuhan 430074, Peoples R China
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GB/T 7714
Zhang, Zehui,Liu, Wujun,Xie, Haibo,et al. An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures[J]. MOLECULES,2011,16(10):8463-8474.
APA Zhang, Zehui,Liu, Wujun,Xie, Haibo,Zhao, Zongbao K.,谢海波,&赵宗保.(2011).An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures.MOLECULES,16(10),8463-8474.
MLA Zhang, Zehui,et al."An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures".MOLECULES 16.10(2011):8463-8474.
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