DICP OpenIR
Subject Area物理化学
An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures
Zhang, Zehui1,3,4; Liu, Wujun1; Xie, Haibo1,2; Zhao, Zongbao K.1,2; Xie HB(谢海波); Zhao ZB(赵宗保)
KeywordSide Reaction Hmf Ionic Liquids 1-butyl-2-(5 '-methyl-2 '-furoyl)Imidazole
Source PublicationMOLECULES
2011-10-01
ISSN1420-3049
DOI10.3390/molecules16108463
Volume16Issue:10Pages:8463-8474
Indexed BySCI
SubtypeArticle
Department18
Funding Project1816
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordPHYSICAL-PROPERTIES ; SOLVENTS ; SOLUBILITY ; CONVERSION ; CATALYSIS ; CHEMISTRY ; SALTS
AbstractAn Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures; A new compound was detected during the production of 5-hydroxymethylfurfural (HMF) from glucose and cellulose in the ionic liquid 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) at high temperatures. Further experiments found that it was derived from the reaction of HMF with [Bmim]Cl. The structure of new compound was established as 1-butyl-2-(5'-methyl-2'-furoyl) imidazole (BMI) based on nuclear magnetic resonance and mass spectrometry analysis, and a possible mechanism for its formation was proposed. Reactions of HMF with other imidazolium-based ionic liquids were performed to check the formation of BMI. Our results provided new insights in terms of side reactions between HMF and imidazolium-based ionic liquids, which should be valuable for designing better processes for the production of furans using biomass and related materials.
Language英语
WOS IDWOS:000296973000024
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115575
Collection中国科学院大连化学物理研究所
Corresponding AuthorXie HB(谢海波); Zhao ZB(赵宗保)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China
4.S Cent Univ Nationalities, Minist Educ, Coll Chem & Mat Sci, Wuhan 430074, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Zehui,Liu, Wujun,Xie, Haibo,et al. An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures[J]. MOLECULES,2011,16(10):8463-8474.
APA Zhang, Zehui,Liu, Wujun,Xie, Haibo,Zhao, Zongbao K.,谢海波,&赵宗保.(2011).An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures.MOLECULES,16(10),8463-8474.
MLA Zhang, Zehui,et al."An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures".MOLECULES 16.10(2011):8463-8474.
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