DICP OpenIR
Subject Area物理化学
Synthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling
Chen, Jinlei1,2; Pang, Qingyu1; Sun, Yanbo2; Li, Xingwei1; Li XW(李兴伟)
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2011-05-06
ISSN待补充
DOI10.1021/jo1025546
Volume76Issue:9Pages:3523-3526
Indexed BySCI ; IC ; CCR
SubtypeArticle
Department2
Funding Project02T3
Contribution Rank2,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordH BOND FUNCTIONALIZATION ; C-H ; HETEROAROMATIC-COMPOUNDS ; ORGANIC-SYNTHESIS ; INTERNAL ALKYNES ; BENZOIC-ACIDS ; ACTIVATION ; CLEAVAGE ; INDOLES ; OXIDANT
AbstractSynthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling; Readily available Pd(II) chloride catalysts can catalyze selective and efficient oxidative coupling between N-aryl-2-aminopyridines and internal alkynes to yield N-(2-pyridyl)indoles. This process involves the ortho C-H activation of N-aryl-2-aminopyridines, and CuCl(2) was used as an oxidant. Compared to our previously reported Rh(III)-catalyzed synthesis of this class of product, this method is advantageous with a wider scope of alkynes and cost-effective Pd(II) catalysts. Molecular oxygen can be used as a terminal oxidant.
Language英语
WOS IDWOS:000289956900062
Citation statistics
Cited Times:72[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115593
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi XW(李兴伟)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Jilin Univ, State Key Lab Theoret & Computat Chem, Inst Theoret Chem, Changchun 130023, Peoples R China
Recommended Citation
GB/T 7714
Chen, Jinlei,Pang, Qingyu,Sun, Yanbo,et al. Synthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling[J]. JOURNAL OF ORGANIC CHEMISTRY,2011,76(9):3523-3526.
APA Chen, Jinlei,Pang, Qingyu,Sun, Yanbo,Li, Xingwei,&李兴伟.(2011).Synthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling.JOURNAL OF ORGANIC CHEMISTRY,76(9),3523-3526.
MLA Chen, Jinlei,et al."Synthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling".JOURNAL OF ORGANIC CHEMISTRY 76.9(2011):3523-3526.
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