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学科主题: 物理化学
题名: Synthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling
作者: Chen, Jinlei1, 2;  Pang, Qingyu1;  Sun, Yanbo2;  Li, Xingwei1
通讯作者: 李兴伟
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2011-05-06
DOI: 10.1021/jo1025546
卷: 76, 期:9, 页:3523-3526
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 02T3
产权排名: 2,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
摘要: Synthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling
研究领域[WOS]: Chemistry
英文摘要: Readily available Pd(II) chloride catalysts can catalyze selective and efficient oxidative coupling between N-aryl-2-aminopyridines and internal alkynes to yield N-(2-pyridyl)indoles. This process involves the ortho C-H activation of N-aryl-2-aminopyridines, and CuCl(2) was used as an oxidant. Compared to our previously reported Rh(III)-catalyzed synthesis of this class of product, this method is advantageous with a wider scope of alkynes and cost-effective Pd(II) catalysts. Molecular oxygen can be used as a terminal oxidant.
关键词[WOS]: H BOND FUNCTIONALIZATION ;  C-H ;  HETEROAROMATIC-COMPOUNDS ;  ORGANIC-SYNTHESIS ;  INTERNAL ALKYNES ;  BENZOIC-ACIDS ;  ACTIVATION ;  CLEAVAGE ;  INDOLES ;  OXIDANT
语种: 英语
WOS记录号: WOS:000289956900062
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115593
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Jilin Univ, State Key Lab Theoret & Computat Chem, Inst Theoret Chem, Changchun 130023, Peoples R China

Recommended Citation:
Chen, Jinlei,Pang, Qingyu,Sun, Yanbo,et al. Synthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling[J]. JOURNAL OF ORGANIC CHEMISTRY,2011,76(9):3523-3526.
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