DICP OpenIR
Subject Area物理化学
A Complexation Promoted Organic N-Hydroxy Catalytic System for Selective Oxidation of Toluene
Zhang, Qiaohong1,2; Chen, Chen1; Xu, Jie1; Wang, Feng1; Gao, Jin1; Xia, Chungu2; Xu J(徐杰)
KeywordComplexation Organic Catalysis Oxidation Synthesis
Source PublicationADVANCED SYNTHESIS & CATALYSIS
2011-02-11
ISSN待补充
DOI10.1002/adsc.201000698
Volume353Issue:2-3Pages:226-230
Indexed BySCI ; IC
SubtypeArticle
Department2
Funding Project204
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Applied ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordEFFICIENT AEROBIC OXIDATION ; LIQUID-PHASE OXIDATION ; MOLECULAR-OXYGEN ; HYDROXYPHTHALIMIDE ; RADICALS ; HYDROCARBONS ; TEMPERATURE ; ACTIVATION ; ALCOHOLS ; ALKANES
AbstractA complexation promoted organic N-Hydroxy catalytic system for selective oxidation of toluene; Complexation was innovatively utilized to design a novel catalytic system for the selective oxidation of toluene, which runs contrary to the traditional definition of organic metal complex catalysis. In the present system, an N-heteroaromatic ring-containing N-hydroxy compound acts as the catalytically active component. Through an electron-withdrawing effect produced by the occurring complexation with proper metal salts, which was characterized by real-time in situ Fourier transform infrared spectra, the activity of the organic molecule could be remarkably improved. The combination of copper(II) chloride with 6-hydroxy-pyrrolo[3,4- b]pyrazine- 5,7-dione showed the best activity, and an inert hydrocarbon such as toluene could be efficiently transformed with 70.9% conversion and 93.5% selectivity to benzoic acid at 90 degrees C within 2 h.
Language英语
WOS IDWOS:000287669600003
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115600
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu J(徐杰)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Qiaohong,Chen, Chen,Xu, Jie,et al. A Complexation Promoted Organic N-Hydroxy Catalytic System for Selective Oxidation of Toluene[J]. ADVANCED SYNTHESIS & CATALYSIS,2011,353(2-3):226-230.
APA Zhang, Qiaohong.,Chen, Chen.,Xu, Jie.,Wang, Feng.,Gao, Jin.,...&徐杰.(2011).A Complexation Promoted Organic N-Hydroxy Catalytic System for Selective Oxidation of Toluene.ADVANCED SYNTHESIS & CATALYSIS,353(2-3),226-230.
MLA Zhang, Qiaohong,et al."A Complexation Promoted Organic N-Hydroxy Catalytic System for Selective Oxidation of Toluene".ADVANCED SYNTHESIS & CATALYSIS 353.2-3(2011):226-230.
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