DICP OpenIR
学科主题物理化学
A Complexation Promoted Organic N-Hydroxy Catalytic System for Selective Oxidation of Toluene
Zhang, Qiaohong1,2; Chen, Chen1; Xu, Jie1; Wang, Feng1; Gao, Jin1; Xia, Chungu2; Xu J(徐杰)
关键词Complexation Organic Catalysis Oxidation Synthesis
刊名ADVANCED SYNTHESIS & CATALYSIS
2011-02-11
ISSN待补充
DOI10.1002/adsc.201000698
353期:2-3页:226-230
收录类别SCI ; IC
文章类型Article
部门归属2
项目归属204
产权排名1,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]EFFICIENT AEROBIC OXIDATION ; LIQUID-PHASE OXIDATION ; MOLECULAR-OXYGEN ; HYDROXYPHTHALIMIDE ; RADICALS ; HYDROCARBONS ; TEMPERATURE ; ACTIVATION ; ALCOHOLS ; ALKANES
英文摘要A complexation promoted organic N-Hydroxy catalytic system for selective oxidation of toluene; Complexation was innovatively utilized to design a novel catalytic system for the selective oxidation of toluene, which runs contrary to the traditional definition of organic metal complex catalysis. In the present system, an N-heteroaromatic ring-containing N-hydroxy compound acts as the catalytically active component. Through an electron-withdrawing effect produced by the occurring complexation with proper metal salts, which was characterized by real-time in situ Fourier transform infrared spectra, the activity of the organic molecule could be remarkably improved. The combination of copper(II) chloride with 6-hydroxy-pyrrolo[3,4- b]pyrazine- 5,7-dione showed the best activity, and an inert hydrocarbon such as toluene could be efficiently transformed with 70.9% conversion and 93.5% selectivity to benzoic acid at 90 degrees C within 2 h.
语种英语
WOS记录号WOS:000287669600003
引用统计
被引频次:20[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115600
专题中国科学院大连化学物理研究所
通讯作者Xu J(徐杰)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Qiaohong,Chen, Chen,Xu, Jie,et al. A Complexation Promoted Organic N-Hydroxy Catalytic System for Selective Oxidation of Toluene[J]. ADVANCED SYNTHESIS & CATALYSIS,2011,353(2-3):226-230.
APA Zhang, Qiaohong.,Chen, Chen.,Xu, Jie.,Wang, Feng.,Gao, Jin.,...&徐杰.(2011).A Complexation Promoted Organic N-Hydroxy Catalytic System for Selective Oxidation of Toluene.ADVANCED SYNTHESIS & CATALYSIS,353(2-3),226-230.
MLA Zhang, Qiaohong,et al."A Complexation Promoted Organic N-Hydroxy Catalytic System for Selective Oxidation of Toluene".ADVANCED SYNTHESIS & CATALYSIS 353.2-3(2011):226-230.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2011KgKnlcIO19.pdf(181KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhang, Qiaohong]的文章
[Chen, Chen]的文章
[Xu, Jie]的文章
百度学术
百度学术中相似的文章
[Zhang, Qiaohong]的文章
[Chen, Chen]的文章
[Xu, Jie]的文章
必应学术
必应学术中相似的文章
[Zhang, Qiaohong]的文章
[Chen, Chen]的文章
[Xu, Jie]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。