DICP OpenIR
Subject Area物理化学
Towards understanding the poor thermal stability of V5+ electrolyte solution in Vanadium Redox Flow Batteries
Vijayakumar, M.1; Li, Liyu1; Graff, Gordon1; Liu, Jun1; Zhang, Huamin2; Yang, Zhenguo1; Hu, Jian Zhi2; ZhenguoYang
KeywordO-17 And V-51 Nmr Vanadium Redox Flow Battery Vanadium Electrolytes V2o5 Precipitation
Source PublicationJOURNAL OF POWER SOURCES
2011-04-01
ISSN待补充
DOI10.1016/j.jpowsour.2010.11.126
Volume196Issue:7Pages:3669-3672
Indexed BySCI
SubtypeArticle
DepartmentDNL17
Funding ProjectDNL17
Contribution Rank2,5
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectElectrochemistry ; Energy & Fuels
WOS Research AreaElectrochemistry ; Energy & Fuels
WOS KeywordCELL ELECTROLYTE ; PRECIPITATION ; PERFORMANCE ; EQUILIBRIA ; STORAGE ; WATER ; VO2+
AbstractTowards understanding the poor thermal stability of V5+ electrolyte solution in Vanadium Redox Flow Batteries; The V5+ electrolyte solution from Vanadium Redox Flow Batteries was studied by variable temperature O-17 and V-51 Nuclear Magnetic Resonance (NMR) spectroscopy and density functional theory (DFT) based computational modeling. It was found that the V5+ species exist as hydrated penta co-ordinated vanadate ion, i.e. [VO2(H2O)(3)](1+). This hydrated structure is not stable at elevated temperature and change into neutral H3VO4 molecule via a deprotonation process and subsequently leading to the observed V2O5 precipitation in Vs electrolyte solutions. (C) 2010 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000289325000040
Citation statistics
Cited Times:121[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115695
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhenguoYang
Affiliation1.Pacific NW Natl Lab, Richland, WA 99352 USA
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Vijayakumar, M.,Li, Liyu,Graff, Gordon,et al. Towards understanding the poor thermal stability of V5+ electrolyte solution in Vanadium Redox Flow Batteries[J]. JOURNAL OF POWER SOURCES,2011,196(7):3669-3672.
APA Vijayakumar, M..,Li, Liyu.,Graff, Gordon.,Liu, Jun.,Zhang, Huamin.,...&ZhenguoYang.(2011).Towards understanding the poor thermal stability of V5+ electrolyte solution in Vanadium Redox Flow Batteries.JOURNAL OF POWER SOURCES,196(7),3669-3672.
MLA Vijayakumar, M.,et al."Towards understanding the poor thermal stability of V5+ electrolyte solution in Vanadium Redox Flow Batteries".JOURNAL OF POWER SOURCES 196.7(2011):3669-3672.
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