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学科主题物理化学
UV Raman Spectroscopic Studies on Rapid Synthesis of AM-6 Zeolite and Formation Mechanism of -V-O-V- Atomic Wires
Guo Mei-Ling1,2; Fan Feng-Tao1; Guo Qiang1,2; Feng Zhao-Chi1; Li Can1; Li C(李灿)
关键词Am-6 Zeolite Uv Raman Spectroscopy Synthesis Mechanism Atomic Wire
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
2011-03-10
ISSN待补充
32期:3页:721-725
收录类别SCI
文章类型Article
部门归属5
项目归属503
产权排名1,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]VANADIUM-OXIDE CATALYSTS ; ETS-10 ; FRAMEWORK
英文摘要UV Raman Spectroscopic Studies on Rapid Synthesis of AM-6 Zeolite and Formation Mechanism of -V-O-V- Atomic Wires; A rapid synthesis(4 h) method of AM-6 zeolite was reported. The effects of the n(K+)/n(V4+) ratio and the pH value of the initial gel on the purity and crystallinity of AM-6 zeolite were investigated. The synthesis conditions optimize at n (K+)/n(V4+) = 3 and pH = 12.5. The formation mechanism of the -V-O-V- atomic wires in AM-6 was monitored by UV Raman spectroscopy in combination with UV-Vis spectroscopy and X-ray diffraction patterns. It turns out that the formation of the VO3- chains composed of corner-sharing VO4 in the silicate gel plays an important role in the formation of -V-O-V- atomic wires in AM-6 crystals.
语种英语
WOS记录号WOS:000289041600047
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115716
专题中国科学院大连化学物理研究所
通讯作者Li C(李灿)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Guo Mei-Ling,Fan Feng-Tao,Guo Qiang,et al. UV Raman Spectroscopic Studies on Rapid Synthesis of AM-6 Zeolite and Formation Mechanism of -V-O-V- Atomic Wires[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2011,32(3):721-725.
APA Guo Mei-Ling,Fan Feng-Tao,Guo Qiang,Feng Zhao-Chi,Li Can,&李灿.(2011).UV Raman Spectroscopic Studies on Rapid Synthesis of AM-6 Zeolite and Formation Mechanism of -V-O-V- Atomic Wires.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,32(3),721-725.
MLA Guo Mei-Ling,et al."UV Raman Spectroscopic Studies on Rapid Synthesis of AM-6 Zeolite and Formation Mechanism of -V-O-V- Atomic Wires".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 32.3(2011):721-725.
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