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学科主题: 物理化学
题名: New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation
作者: Han, Mei-Ling1, 2;  Hu, Xiang-Ping1;  Huang, Jia-Di1;  Chen, Li-Gong2;  Zheng, Zhuo1
通讯作者: 胡向平
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2011-01-31
DOI: 10.1016/j.tetasy.2011.01.017
卷: 22, 期:2, 页:222-225
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 2T2
产权排名: 2,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic ;  Chemistry, Physical
摘要: New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation
研究领域[WOS]: Chemistry
英文摘要: A series of chiral amino alcohols have been prepared from cheap and readily available (S)-1-phenylethylamine through a one-step transformation. The ability of these newly developed amino alcohols as chiral ligands was evaluated in the Ru-catalyzed asymmetric transfer hydrogenation of aromatic alkyl ketones, providing chiral secondary alcohols with good to excellent conversions (71-100%) and moderate to good enantioselectivities (67-95% ee). The results also showed that the structure of these amino alcohols has a significant influence on the conversion and enantioselectivity. (C) 2011 Elsevier Ltd. All rights reserved.
关键词[WOS]: ALCOHOL)-CATALYZED TRANSFER HYDROGENATION ;  AROMATIC KETONES ;  ENANTIOSELECTIVITY ;  COMPLEXES ;  ORIGIN
语种: 英语
WOS记录号: WOS:000288890800016
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115728
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
2.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China

Recommended Citation:
Han, Mei-Ling,Hu, Xiang-Ping,Huang, Jia-Di,et al. New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation[J]. TETRAHEDRON-ASYMMETRY,2011,22(2):222-225.
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