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学科主题: 物理化学
题名: Selective Hydrogenation of Acetylene over a MoP Catalyst
作者: Zhou Guilin1;  Wang Puguang2;  Jiang Zongxuan1;  Ying Pinliang1;  Li Can1
通讯作者: 李灿
关键词: molybdenum phosphide ;  acetylene ;  selective hydrogenation ;  ethylene
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2011
DOI: 10.1016/S1872-2067(10)60155-6
卷: 32, 期:1, 页:27-30
收录类别: SCI
文章类型: Article
部门归属: 5
项目归属: 503
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
摘要: Selective Hydrogenation of Acetylene over a MoP Catalyst
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: A MoP catalyst was prepared by high temperature hydrogen reduction. Its properties were investigated by X-ray diffraction and in-situ X-ray photoelectron spectroscopy. It was used for the selective catalytic hydrogenation of acetylene. The results indicated that MoP is formed by hydrogen reduction at 650 degrees C. The prepared MoP catalyst contained high valence molybdenum and phosphorus species. The catalyst is a bifunctional catalyst, which includes a hydrogenation center and an electron-deficient center. Ethylene selectivity can exceed 73% when the acetylene conversion is higher than 99%.
关键词[WOS]: HYDRODESULFURIZATION ;  PERFORMANCE ;  ALPHA-AL2O3 ;  ETHYLENE ;  NI2P
语种: 英语
WOS记录号: WOS:000287107200003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115740
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Shannxi Yanchang Petr Co Ltd, Xian 710075, Shannxi, Peoples R China

Recommended Citation:
Zhou Guilin,Wang Puguang,Jiang Zongxuan,et al. Selective Hydrogenation of Acetylene over a MoP Catalyst[J]. CHINESE JOURNAL OF CATALYSIS,2011,32(1):27-30.
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