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学科主题: 物理化学
题名: Phosphotungstic Acid Encapsulated in Metal-Organic Framework as Catalysts for Carbohydrate Dehydration to 5-Hydroxymethylfurfural
作者: Zhang, Yanmei1, 2;  Degirmenci, Volkan2;  Li, Can1;  Hensen, Emiel J. M.2
通讯作者: 李灿 ;  EmielJ.M.Hensen
关键词: biomass ;  carbohydrates ;  heterogeneous catalysis ;  metal-organic frameworks ;  solid acids
刊名: CHEMSUSCHEM
发表日期: 2011
DOI: 10.1002/cssc.201000284
卷: 4, 期:1, 页:59-64
收录类别: SCI
文章类型: Article
部门归属: 5
项目归属: 503
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
摘要: Phosphotungstic Acid Encapsulated in Metal-Organic Framework as Catalysts for Carbohydrate Dehydration to 5-Hydroxymethylfurfural
研究领域[WOS]: Chemistry
英文摘要: MIL-101, a chromium-based metal-organic framework, is known for its very large pore size, large surface area and good stability. However, applications of this material in catalysis are still limited. 5-Hydroxymethylfurfural (HMF) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. Phosphotungstic acid, H(3)PW(12)O(40) (PTA), encapsulated in MIL-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. The results demonstrate that PTA/MIL-101 is effective for HMF production from fructose in DMSO and can be reused. This is the first example of the application of a metal-organic framework in carbohydrate dehydration.
关键词[WOS]: MESOPOROUS SILICA ;  HYDROGEN STORAGE ;  DRUG-DELIVERY ;  SURFACE-AREA ;  IONIC LIQUID ;  GIANT PORES ;  D-FRUCTOSE ;  BIOMASS ;  SITES ;  OXIDATION
语种: 英语
WOS记录号: WOS:000287138900010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115742
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

Recommended Citation:
Zhang, Yanmei,Degirmenci, Volkan,Li, Can,et al. Phosphotungstic Acid Encapsulated in Metal-Organic Framework as Catalysts for Carbohydrate Dehydration to 5-Hydroxymethylfurfural[J]. CHEMSUSCHEM,2011,4(1):59-64.
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