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学科主题: 物理化学
题名: Recyclable enamine catalysts for asymmetric direct cross-aldol reaction of aldehydes in emulsion media
作者: Gao, Qiang1, 2;  Liu, Yan1;  Lu, Sheng-Mei1;  Li, Jun1;  Li, Can1
通讯作者: 李灿
刊名: GREEN CHEMISTRY
发表日期: 2011
DOI: 10.1039/c1gc15473g
卷: 13, 期:8, 页:1983-1985
收录类别: SCI
文章类型: Article
部门归属: 5
项目归属: 503
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
摘要: Recyclable Enamine Catalysts for Asymmetric Direct Cross-aldol Reaction of Aldehydes in Emulsion Media
研究领域[WOS]: Chemistry
英文摘要: Highly diastereo- and enantioselective cross-aldol reactions of aldehydes (> 20 : 1 dr, 99% ee), catalyzed by chiral diamine-polyoxometalate acid combined enamine catalysts in emulsion media, are reported. This type of catalysts can be recycled several times without significant deterioration of activity and selectivity.
关键词[WOS]: AMINE-POLYOXOMETALATE HYBRIDS ;  HIGHLY EFFICIENT ;  PYRROLIDINE SULFONAMIDE ;  WATER ;  ORGANOCATALYST ;  PROLINE ;  POLYSTYRENE ;  DROPLETS ;  MANNICH
语种: 英语
WOS记录号: WOS:000293518300005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115756
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Gao, Qiang,Liu, Yan,Lu, Sheng-Mei,et al. Recyclable enamine catalysts for asymmetric direct cross-aldol reaction of aldehydes in emulsion media[J]. GREEN CHEMISTRY,2011,13(8):1983-1985.
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