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学科主题物理化学
Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst
Zeng, Ju-Lan1; Yu, Sai-Bo2; Cao, Zhong1; Yang, Dao-Wu1; Sun, Li-Xian3; Zhang, Ling1; Zhang, Xiong-Fei1; ZengJulan; YuSai-Bo
关键词Enantioselective Catalyst Crystal Structure Molar Heat Capacity Thermodynamic Functions
刊名JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2011-09-01
ISSN1388-6150
DOI10.1007/s10973-011-1486-9
105期:3页:961-968
收录类别SCI
文章类型Article
部门归属DNL19
项目归属1903
产权排名3,5
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]FERROCENE DERIVATIVES ; CHIRAL FERROCENYLPHOSPHINES ; ASYMMETRIC-SYNTHESIS ; LIGANDS ; POLYMERS
英文摘要Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst; A new potential enantioselective catalyst derived from ferrocene, 1-{(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyl}-benzimidazole (DPFEB), was prepared and its absolute structure was characterized by means of single crystal X-ray diffraction. The molar heat capacity of DPFEB was measured by means of temperature modulated differential scanning calorimetry over the temperature range of 200-530 K, and the thermodynamic functions of [H (T) - H (298.15)] and [S (T) - S (298.15)] were calculated. Further more, thermogravimetry experiment revealed that DPFEB exhibited a three step thermal decomposition process with the final residual of 28.7%.
语种英语
WOS记录号WOS:000294014000026
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115758
专题中国科学院大连化学物理研究所
通讯作者ZengJulan; YuSai-Bo
作者单位1.Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China
2.China Tobacco Hunan Ind Corp, Changsha 410007, Hunan, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
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GB/T 7714
Zeng, Ju-Lan,Yu, Sai-Bo,Cao, Zhong,et al. Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2011,105(3):961-968.
APA Zeng, Ju-Lan.,Yu, Sai-Bo.,Cao, Zhong.,Yang, Dao-Wu.,Sun, Li-Xian.,...&YuSai-Bo.(2011).Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,105(3),961-968.
MLA Zeng, Ju-Lan,et al."Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 105.3(2011):961-968.
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