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学科主题: 物理化学
题名: Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst
作者: Zeng, Ju-Lan1;  Yu, Sai-Bo2;  Cao, Zhong1;  Yang, Dao-Wu1;  Sun, Li-Xian3;  Zhang, Ling1;  Zhang, Xiong-Fei1
通讯作者: ZengJulan ;  YuSai-Bo
关键词: Enantioselective catalyst ;  Crystal structure ;  Molar heat capacity ;  Thermodynamic functions
刊名: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
发表日期: 2011-09-01
DOI: 10.1007/s10973-011-1486-9
卷: 105, 期:3, 页:961-968
收录类别: SCI
文章类型: Article
部门归属: DNL19
项目归属: 1903
产权排名: 3,5
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
摘要: Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst
研究领域[WOS]: Chemistry
英文摘要: A new potential enantioselective catalyst derived from ferrocene, 1-{(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyl}-benzimidazole (DPFEB), was prepared and its absolute structure was characterized by means of single crystal X-ray diffraction. The molar heat capacity of DPFEB was measured by means of temperature modulated differential scanning calorimetry over the temperature range of 200-530 K, and the thermodynamic functions of [H (T) - H (298.15)] and [S (T) - S (298.15)] were calculated. Further more, thermogravimetry experiment revealed that DPFEB exhibited a three step thermal decomposition process with the final residual of 28.7%.
关键词[WOS]: FERROCENE DERIVATIVES ;  CHIRAL FERROCENYLPHOSPHINES ;  ASYMMETRIC-SYNTHESIS ;  LIGANDS ;  POLYMERS
语种: 英语
WOS记录号: WOS:000294014000026
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115758
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China
2.China Tobacco Hunan Ind Corp, Changsha 410007, Hunan, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China

Recommended Citation:
Zeng, Ju-Lan,Yu, Sai-Bo,Cao, Zhong,et al. Synthesize, crystal structure, heat capacities and thermodynamic properties of a potential enantioselective catalyst[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2011,105(3):961-968.
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