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学科主题: 物理化学
题名: Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs
作者: Jiang, Chun-Hong1, 2;  Song, Li-Fang1, 2;  Jiao, Cheng-Li1, 2;  Zhang, Jian1;  Sun, Li-Xian1;  Xu, Fen3;  Zhang, Huan-Zhi1;  Xu, Qing-Yang1;  Gabelica, Zelimir4
通讯作者: 孙立贤 ;  XuFen
关键词: Ca-MOF ;  Mn-II-MOF ;  Molar heat capacity ;  TG ;  Temperature-modulated DSC
刊名: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
发表日期: 2011-03-01
DOI: 10.1007/s10973-010-1197-7
卷: 103, 期:3, 页:1095-1103
收录类别: SCI
文章类型: Article
部门归属: DNL19
项目归属: 1903
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
摘要: Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs
研究领域[WOS]: Chemistry
英文摘要: Two metal-organic frameworks, Ca(2,6-NDC)(DMF) (1) and Mn-3(2,6-NDC)(3)(DMF)(4) (2) (where 2,6-NDC = 2,6-naphthalene dicarboxylate and DMF = N,N'-dimethylformamide) have been solvothermally synthesized under optimized conditions and characterized by X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, and TG analysis. The thermal decomposition characteristics were investigated under air atmosphere from 300 to 1,170 K (for 1) and from 300 to 971 K (for 2). The molar heat capacities were measured from 198 to 548 K (for 1) and from 198 to 448 K (for 2) by temperature modulated differential scanning calorimetry (TMDSC) for the first time. The fundamental thermodynamic parameters such as entropy and enthalpy variations with temperature were calculated based on the experimentally determined molar heat capacities.
关键词[WOS]: METAL-ORGANIC FRAMEWORKS ;  HYDROGEN SORPTION ;  GAS-ADSORPTION ;  PHOTOLUMINESCENCE ;  STORAGE ;  SEPARATION ;  CATALYSTS ;  CO2
语种: 英语
WOS记录号: WOS:000287712400040
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115776
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
4.Univ Haute Alsace, ENSCMu, Lab LPI GSEC, F-68094 Mulhouse, France

Recommended Citation:
Jiang, Chun-Hong,Song, Li-Fang,Jiao, Cheng-Li,et al. Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2011,103(3):1095-1103.
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