DICP OpenIR
学科主题物理化学
Hydrogen production for micro-fuel-cell from activated Al-Sn-Zn-X (X: hydride or halide) mixture in water
Fan, Mei Qiang1,2; Sun, Li Xian1; Xu, Fen3; Sun LX(孙立贤)
关键词Hydrolysis Aluminum Alloy Hydride Halide
刊名RENEWABLE ENERGY
2011-02-01
ISSN0960-1481
DOI10.1016/j.renene.2010.07.006
36期:2页:519-524
收录类别SCI
文章类型Article
部门归属DNL19
项目归属1903
产权排名1,1
WOS标题词Science & Technology ; Technology
类目[WOS]Energy & Fuels
研究领域[WOS]Energy & Fuels
关键词[WOS]CATHODIC POLARIZATION ; ALUMINUM ; GENERATION ; ALLOYS ; HYDROLYSIS ; METAL ; GAS
英文摘要Hydrogen production for micro-fuel-cell from activated Al-Sn-Zn-X (X: hydride or halide) mixture in water; A systematic investigation of hydrogen production from milled Al-Sn-Zn-X (X: hydride or halide) mixtures in pure water was performed at room temperature. The hydrolysis mechanism of the mixtures was based on the work of micro-galvanic cell between aluminum and tin in water where aluminum reacted with water to generate AlOOH (Boehmite) and hydrogen. It was found that many effects such as milling time, temperature, additives and mass ratio had a significant role in the hydrogen production rate, especially that of the additives (hydride or halide) led to reduction of crystallite size and accumulation of uniform mixing. They also produced a lot of heat and the conductive ions which simulated the work of micro-galvanic cell. The milled Al-Sn-Zn-X (X: hydride or halide) mixtures had high reactivity and Al-Sn-Zn-MgH2 mixture produced 790 mL g(-1) hydrogen in 5 min of the hydrolysis reaction with the activation energy of 17.570 kJ mol(-1), corresponding to 7.04 wt.% hydrogen excluding water mass. Therefore, a new method of CO2 free and safe hydrogen production for micro-fuel-cell was obtained from the activated aluminum alloys in water. (c) 2010 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000283831100013
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115777
专题中国科学院大连化学物理研究所
通讯作者Sun LX(孙立贤)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.China Jiliang Univ, Dept Mat Sci & Engn, Hangzhou 310018, Peoples R China
3.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
推荐引用方式
GB/T 7714
Fan, Mei Qiang,Sun, Li Xian,Xu, Fen,et al. Hydrogen production for micro-fuel-cell from activated Al-Sn-Zn-X (X: hydride or halide) mixture in water[J]. RENEWABLE ENERGY,2011,36(2):519-524.
APA Fan, Mei Qiang,Sun, Li Xian,Xu, Fen,&孙立贤.(2011).Hydrogen production for micro-fuel-cell from activated Al-Sn-Zn-X (X: hydride or halide) mixture in water.RENEWABLE ENERGY,36(2),519-524.
MLA Fan, Mei Qiang,et al."Hydrogen production for micro-fuel-cell from activated Al-Sn-Zn-X (X: hydride or halide) mixture in water".RENEWABLE ENERGY 36.2(2011):519-524.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2011abg2s99piy.pdf(884KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Fan, Mei Qiang]的文章
[Sun, Li Xian]的文章
[Xu, Fen]的文章
百度学术
百度学术中相似的文章
[Fan, Mei Qiang]的文章
[Sun, Li Xian]的文章
[Xu, Fen]的文章
必应学术
必应学术中相似的文章
[Fan, Mei Qiang]的文章
[Sun, Li Xian]的文章
[Xu, Fen]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。