DICP OpenIR
学科主题物理化学
Heat capacities and thermodynamic properties of MgNDC
Song, Li-Fang1,2; Jiao, Cheng-Li1,2; Jiang, Chun-Hong1,2; Zhang, Jian1; Sun, Li-Xian1; Xu, Fen3; Jiao, Qing-Zhu3; Xing, Yong-Heng3; Huang, F. L.4; Du, Yong5; Cao, Zhong6; Li, Fen2; Zhao, Jijun7; Sun LX(孙立贤); XuFen
关键词Magnesium Tmdsc Metal-organic Frameworks Molar Heat Capacity Tg
刊名JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2011
ISSN1388-6150
DOI10.1007/s10973-010-0777-x
103期:1页:365-372
收录类别SCI
文章类型Article
部门归属DNL19
项目归属1903
产权排名1,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]METAL-ORGANIC FRAMEWORKS ; COORDINATION POLYMER ; MODULATED DSC
英文摘要Heat capacities and thermodynamic properties of MgNDC; One-three-dimensional metal-organic frameworks Mg-1.5(C12H6O4)(1.5)(C3H7NO)(2) (MgNDC) has been synthesized solvothermally and characterized by single crystal XRD, powder XRD, FT-IR spectra. The low-temperature molar heat capacities of MgNDC were measured by temperature modulated differential scanning calorimetry (TMDSC) over the temperature range from 205 to 470 K for the first time. No phase transition or thermal anomaly was observed in the experimental temperature range. The thermodynamic parameters of MgNDC such as entropy and enthalpy relative to reference temperature of 298.15 K were derived based on the above molar heat capacities data. Moreover, the thermal stability and decomposition of MgNDC was further investigated through thermogravimetry (TG)-mass spectrometer (MS). Three stages of mass loss were observed in the TG curve. TG-MS curve indicated that the oxidative degradation products of MgNDC are mainly H2O, CO2, NO, and NO2.
语种英语
WOS记录号WOS:000287714400053
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115778
专题中国科学院大连化学物理研究所
通讯作者Sun LX(孙立贤); XuFen
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
4.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
5.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
6.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China
7.Dalian Univ Technol, Lab Mat Modificat Laser Electron & Ion Beams, Dalian 116024, Peoples R China
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GB/T 7714
Song, Li-Fang,Jiao, Cheng-Li,Jiang, Chun-Hong,et al. Heat capacities and thermodynamic properties of MgNDC[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2011,103(1):365-372.
APA Song, Li-Fang.,Jiao, Cheng-Li.,Jiang, Chun-Hong.,Zhang, Jian.,Sun, Li-Xian.,...&XuFen.(2011).Heat capacities and thermodynamic properties of MgNDC.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,103(1),365-372.
MLA Song, Li-Fang,et al."Heat capacities and thermodynamic properties of MgNDC".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 103.1(2011):365-372.
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