中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
学科主题: 物理化学
题名: Heat capacities and thermodynamic properties of MgNDC
作者: Song, Li-Fang1, 2;  Jiao, Cheng-Li1, 2;  Jiang, Chun-Hong1, 2;  Zhang, Jian1;  Sun, Li-Xian1;  Xu, Fen3;  Jiao, Qing-Zhu3;  Xing, Yong-Heng3;  Huang, F. L.4;  Du, Yong5;  Cao, Zhong6;  Li, Fen2;  Zhao, Jijun7
通讯作者: 孙立贤 ;  XuFen
关键词: Magnesium ;  TMDSC ;  Metal-organic frameworks ;  Molar heat capacity ;  TG
刊名: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
发表日期: 2011
DOI: 10.1007/s10973-010-0777-x
卷: 103, 期:1, 页:365-372
收录类别: SCI
文章类型: Article
部门归属: DNL19
项目归属: 1903
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
摘要: Heat capacities and thermodynamic properties of MgNDC
研究领域[WOS]: Chemistry
英文摘要: One-three-dimensional metal-organic frameworks Mg-1.5(C12H6O4)(1.5)(C3H7NO)(2) (MgNDC) has been synthesized solvothermally and characterized by single crystal XRD, powder XRD, FT-IR spectra. The low-temperature molar heat capacities of MgNDC were measured by temperature modulated differential scanning calorimetry (TMDSC) over the temperature range from 205 to 470 K for the first time. No phase transition or thermal anomaly was observed in the experimental temperature range. The thermodynamic parameters of MgNDC such as entropy and enthalpy relative to reference temperature of 298.15 K were derived based on the above molar heat capacities data. Moreover, the thermal stability and decomposition of MgNDC was further investigated through thermogravimetry (TG)-mass spectrometer (MS). Three stages of mass loss were observed in the TG curve. TG-MS curve indicated that the oxidative degradation products of MgNDC are mainly H2O, CO2, NO, and NO2.
关键词[WOS]: METAL-ORGANIC FRAMEWORKS ;  COORDINATION POLYMER ;  MODULATED DSC
语种: 英语
WOS记录号: WOS:000287714400053
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115778
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2011Fl7PC3ODGw.pdf(437KB)----开放获取--View Download

作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
4.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
5.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
6.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China
7.Dalian Univ Technol, Lab Mat Modificat Laser Electron & Ion Beams, Dalian 116024, Peoples R China

Recommended Citation:
Song, Li-Fang,Jiao, Cheng-Li,Jiang, Chun-Hong,et al. Heat capacities and thermodynamic properties of MgNDC[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2011,103(1):365-372.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Song, Li-Fang]'s Articles
 [Jiao, Cheng-Li]'s Articles
 [Jiang, Chun-Hong]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Song, Li-Fang]‘s Articles
 [Jiao, Cheng-Li]‘s Articles
 [Jiang, Chun-Hong]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 2011Fl7PC3ODGw.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace