DICP OpenIR
Subject Area物理化学
Heat capacities and thermodynamic properties of MgNDC
Song, Li-Fang1,2; Jiao, Cheng-Li1,2; Jiang, Chun-Hong1,2; Zhang, Jian1; Sun, Li-Xian1; Xu, Fen3; Jiao, Qing-Zhu3; Xing, Yong-Heng3; Huang, F. L.4; Du, Yong5; Cao, Zhong6; Li, Fen2; Zhao, Jijun7; Sun LX(孙立贤); XuFen
KeywordMagnesium Tmdsc Metal-organic Frameworks Molar Heat Capacity Tg
Source PublicationJOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2011
ISSN1388-6150
DOI10.1007/s10973-010-0777-x
Volume103Issue:1Pages:365-372
Indexed BySCI
SubtypeArticle
DepartmentDNL19
Funding Project1903
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Analytical ; Chemistry, Physical
WOS Research AreaChemistry
WOS KeywordMETAL-ORGANIC FRAMEWORKS ; COORDINATION POLYMER ; MODULATED DSC
AbstractHeat capacities and thermodynamic properties of MgNDC; One-three-dimensional metal-organic frameworks Mg-1.5(C12H6O4)(1.5)(C3H7NO)(2) (MgNDC) has been synthesized solvothermally and characterized by single crystal XRD, powder XRD, FT-IR spectra. The low-temperature molar heat capacities of MgNDC were measured by temperature modulated differential scanning calorimetry (TMDSC) over the temperature range from 205 to 470 K for the first time. No phase transition or thermal anomaly was observed in the experimental temperature range. The thermodynamic parameters of MgNDC such as entropy and enthalpy relative to reference temperature of 298.15 K were derived based on the above molar heat capacities data. Moreover, the thermal stability and decomposition of MgNDC was further investigated through thermogravimetry (TG)-mass spectrometer (MS). Three stages of mass loss were observed in the TG curve. TG-MS curve indicated that the oxidative degradation products of MgNDC are mainly H2O, CO2, NO, and NO2.
Language英语
WOS IDWOS:000287714400053
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115778
Collection中国科学院大连化学物理研究所
Corresponding AuthorSun LX(孙立贤); XuFen
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
4.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
5.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
6.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China
7.Dalian Univ Technol, Lab Mat Modificat Laser Electron & Ion Beams, Dalian 116024, Peoples R China
Recommended Citation
GB/T 7714
Song, Li-Fang,Jiao, Cheng-Li,Jiang, Chun-Hong,et al. Heat capacities and thermodynamic properties of MgNDC[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2011,103(1):365-372.
APA Song, Li-Fang.,Jiao, Cheng-Li.,Jiang, Chun-Hong.,Zhang, Jian.,Sun, Li-Xian.,...&XuFen.(2011).Heat capacities and thermodynamic properties of MgNDC.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,103(1),365-372.
MLA Song, Li-Fang,et al."Heat capacities and thermodynamic properties of MgNDC".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 103.1(2011):365-372.
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