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学科主题: 物理化学
题名: Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands
作者: Chen, Kai1;  Sun, Zhen-Gang1;  Zhu, Yan-Yu1;  Liu, Zhong-Min2;  Tong, Fei1;  Dong, Da-Peng1;  Li, Jing1;  Jiao, Cheng-Qi1;  Li, Chao1;  Wang, Cheng-Lin1
通讯作者: Zhen-GangSun
刊名: CRYSTAL GROWTH & DESIGN
发表日期: 2011-10-01
DOI: 10.1021/cg200876t
卷: 11, 期:10, 页:4623-4631
收录类别: SCI
文章类型: Article
部门归属: DNL12
项目归属: DNL12
产权排名: 2,4
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Crystallography ;  Materials Science, Multidisciplinary
摘要: Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands
研究领域[WOS]: Chemistry ;  Crystallography ;  Materials Science
英文摘要: By introduction of three differently structured rigid aromatic carboxylic acids as second organic ligands, three novel lead(II) carboxyphosphonates with 3D framework structures, namely, [Pb-4(FIL)(bts)(2)(H2O)]center dot 2H(2)O (1), [Pb-4(HL)-(L)(bdc)(1.5)]center dot 2H(2)O (2), and [Pb-3(HL)(2)(Hssc)]center dot 2H(2)O (3) (H3L = H2O3PCH2-NC5H9-COOH, NaH(2)bts = NaO3SC6H3-(COOH)(2), H(2)bdc = HOOCC6H4COOH, H(3)ssc = HOOCC6H3-(SO3H)(OH)), have been synthesized under hydrothermal conditions and structurally characterized. The structure of compound 1 features a 3D network built by the cross-linking of ID double chains of lead(II) phosphonates and 2D layers of lead(II) carboxylate-sulfonate. Compound 2 exhibits a 3D structure built up from Pb-II polyhedra, carboxyphosphonates, and bdc(2-) ions. The structure of compound 3 can be described as a 3D framework type. The Pb(1)O-6, Pb(2)O-4, Pb(3)O-5, and CPO3 polyhedra are interconnected to form infinite double chain and the second linkers are hung in this chain, which is further connected to adjacent chains through carboxyphosphonate ligands to form a 3D framework structure. The luminescence properties of compounds 1-3 have also been studied.
关键词[WOS]: LANTHANIDE OXALATOPHOSPHONATES ;  HYDROTHERMAL SYNTHESIS ;  COORDINATION POLYMERS ;  THERMAL-STABILITY ;  HELICAL CHAINS ;  PHOSPHONATE ;  DIPHOSPHONATES ;  RESONANCE ;  HYBRIDS ;  SERIES
语种: 英语
WOS记录号: WOS:000295488200055
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115850
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Normal Univ, Inst Chem Functionalized Mat, Sch Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Chen, Kai,Sun, Zhen-Gang,Zhu, Yan-Yu,et al. Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands[J]. CRYSTAL GROWTH & DESIGN,2011,11(10):4623-4631.
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