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学科主题物理化学
Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands
Chen, Kai1; Sun, Zhen-Gang1; Zhu, Yan-Yu1; Liu, Zhong-Min2; Tong, Fei1; Dong, Da-Peng1; Li, Jing1; Jiao, Cheng-Qi1; Li, Chao1; Wang, Cheng-Lin1; Zhen-GangSun
刊名CRYSTAL GROWTH & DESIGN
2011-10-01
ISSN待补充
DOI10.1021/cg200876t
11期:10页:4623-4631
收录类别SCI
文章类型Article
部门归属DNL12
项目归属DNL12
产权排名2,4
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Crystallography ; Materials Science
关键词[WOS]LANTHANIDE OXALATOPHOSPHONATES ; HYDROTHERMAL SYNTHESIS ; COORDINATION POLYMERS ; THERMAL-STABILITY ; HELICAL CHAINS ; PHOSPHONATE ; DIPHOSPHONATES ; RESONANCE ; HYBRIDS ; SERIES
英文摘要Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands; By introduction of three differently structured rigid aromatic carboxylic acids as second organic ligands, three novel lead(II) carboxyphosphonates with 3D framework structures, namely, [Pb-4(FIL)(bts)(2)(H2O)]center dot 2H(2)O (1), [Pb-4(HL)-(L)(bdc)(1.5)]center dot 2H(2)O (2), and [Pb-3(HL)(2)(Hssc)]center dot 2H(2)O (3) (H3L = H2O3PCH2-NC5H9-COOH, NaH(2)bts = NaO3SC6H3-(COOH)(2), H(2)bdc = HOOCC6H4COOH, H(3)ssc = HOOCC6H3-(SO3H)(OH)), have been synthesized under hydrothermal conditions and structurally characterized. The structure of compound 1 features a 3D network built by the cross-linking of ID double chains of lead(II) phosphonates and 2D layers of lead(II) carboxylate-sulfonate. Compound 2 exhibits a 3D structure built up from Pb-II polyhedra, carboxyphosphonates, and bdc(2-) ions. The structure of compound 3 can be described as a 3D framework type. The Pb(1)O-6, Pb(2)O-4, Pb(3)O-5, and CPO3 polyhedra are interconnected to form infinite double chain and the second linkers are hung in this chain, which is further connected to adjacent chains through carboxyphosphonate ligands to form a 3D framework structure. The luminescence properties of compounds 1-3 have also been studied.
语种英语
WOS记录号WOS:000295488200055
引用统计
被引频次:35[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115850
专题中国科学院大连化学物理研究所
通讯作者Zhen-GangSun
作者单位1.Liaoning Normal Univ, Inst Chem Functionalized Mat, Sch Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Chen, Kai,Sun, Zhen-Gang,Zhu, Yan-Yu,et al. Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands[J]. CRYSTAL GROWTH & DESIGN,2011,11(10):4623-4631.
APA Chen, Kai.,Sun, Zhen-Gang.,Zhu, Yan-Yu.,Liu, Zhong-Min.,Tong, Fei.,...&Zhen-GangSun.(2011).Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands.CRYSTAL GROWTH & DESIGN,11(10),4623-4631.
MLA Chen, Kai,et al."Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands".CRYSTAL GROWTH & DESIGN 11.10(2011):4623-4631.
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