DICP OpenIR
Subject Area物理化学
Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains
Dong, Da-Peng1; Liu, Lei1; Sun, Zhen-Gang1; Jiao, Cheng-Qi1; Liu, Zhong-Min2; Li, Chao1; Zhu, Yan-Yu1; Chen, Kai1; Wang, Cheng-Lin1; Zhen-GangSun
Source PublicationCRYSTAL GROWTH & DESIGN
2011-12-01
ISSN待补充
DOI10.1021/cg2009368
Volume11Issue:12Pages:5346-5354
Indexed BySCI
SubtypeArticle
DepartmentDNL12
Funding ProjectDNL12
Contribution Rank2,5
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Crystallography ; Materials Science
WOS KeywordMETAL PHOSPHONATE CHEMISTRY ; CARBOXYLATE-PHOSPHONATES ; COORDINATION POLYMERS ; SPONTANEOUS RESOLUTION ; ORGANIC FRAMEWORK ; BUILDING-BLOCKS ; POROUS SOLIDS ; ZEOLITE-TYPE ; SERIES ; STATE
AbstractSynthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains; Using the heptadentate ligand hedpH(4) (1-hydroxyethylidenediphosphonic acid) and lanthanide chloride, two isomorphous series of coordination frameworks of the general formula [NH4] [Ln(hedp)(H2O)]center dot H2O (series 1, orthorhombic P2(1)2(1)2(1), Ln = La (1), Ce (2), Pr (3), Nd (4)) and [NH4] [Ln(hedp)(H2O)] (series 2, orthorhombic Pnma, Ln = Sm (5), Eu (6), Gd (7), Tb (8), Dy (9), Y (10), Er (11)) have been assembled and characterized with IR, elemental analysis, thermogravimetric analysis, and single-crystal and powder X-ray diffraction methods. In both series, each inorganic chain based on LnO(8) and CPO3 polyhedra are interconnected through phosphonate ligands to form chiral and achiral 3D open-framework structures with left- and right-handed helical chains. Meanwhile, the two series also exhibit two types of 3D framework structures with similar network topologies. The crystal water molecule plays an important role to induce chiral structure and affects the crystal packing of the molecules with extensive hydrogen bonding. The luminescence properties of compounds 5, 6, 8 and 9 and the magnetic property of compound 7 have also been studied.
Language英语
WOS IDWOS:000297609100024
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115851
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhen-GangSun
Affiliation1.Liaoning Normal Univ, Sch Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Dong, Da-Peng,Liu, Lei,Sun, Zhen-Gang,et al. Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains[J]. CRYSTAL GROWTH & DESIGN,2011,11(12):5346-5354.
APA Dong, Da-Peng.,Liu, Lei.,Sun, Zhen-Gang.,Jiao, Cheng-Qi.,Liu, Zhong-Min.,...&Zhen-GangSun.(2011).Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains.CRYSTAL GROWTH & DESIGN,11(12),5346-5354.
MLA Dong, Da-Peng,et al."Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains".CRYSTAL GROWTH & DESIGN 11.12(2011):5346-5354.
Files in This Item:
File Name/Size DocType Version Access License
2011FSRBqahgtU.pdf(4288KB) 开放获取--Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Dong, Da-Peng]'s Articles
[Liu, Lei]'s Articles
[Sun, Zhen-Gang]'s Articles
Baidu academic
Similar articles in Baidu academic
[Dong, Da-Peng]'s Articles
[Liu, Lei]'s Articles
[Sun, Zhen-Gang]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Dong, Da-Peng]'s Articles
[Liu, Lei]'s Articles
[Sun, Zhen-Gang]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.