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学科主题: 物理化学
题名: Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture
作者: Zhu, Yan-Yu1;  Sun, Zhen-Gang1;  Tong, Fei1;  Liu, Zhong-Min2;  Huang, Cui-Ying1;  Wang, Wei-Nan1;  Jiao, Cheng-Qi1;  Wang, Cheng-Lin1;  Li, Chao1;  Chen, Kai1
通讯作者: Zhen-GangSun
刊名: DALTON TRANSACTIONS
发表日期: 2011
DOI: 10.1039/c0dt01781g
卷: 40, 期:20, 页:5584-5590
收录类别: SCI
文章类型: Article
部门归属: DNL12
项目归属: DNL12
产权排名: 2,4
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
摘要: Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture
研究领域[WOS]: Chemistry
英文摘要: Eleven new lanthanide oxalatophosphonate hybrids with a 2D layered structures, namely, [Ln(H3L)(C2O4)]center dot 2H(2)O (Ln = La-Dy, Er and Y, H4L = C6H5CH2N(CH2PO3H2)(2)), have been synthesized under hydrothermal conditions and structurally characterized by X-ray single-crystal diffraction, X-ray powder diffraction, infrared spectroscopy, elemental analysis and thermogravimetric analysis. Compounds 1-11 are isomorphous and they exhibit a 2D framework structure. Two {LnO(8)} polyhedra and four {CPO3} tetrahedra are interconnected into a unit via corner-sharing, and the so-built units are bridged by the oxalate anions into a layer. The result of connections in this manner is the formation of a 24-atom window. The thermal stabilities and guest desorption-sorption properties of compounds 1-11 have been investigated. The luminescent properties of compounds 5, 6, 8 and 9 have also been studied.
关键词[WOS]: INITIO STRUCTURE DETERMINATION ;  FRAMEWORKS MIL-N ;  COORDINATION POLYMERS ;  ORGANIC FRAMEWORKS ;  MOLECULAR RECOGNITION ;  VISIBLE LUMINESCENCE ;  METAL PHOSPHONATES ;  COMPLEXES ;  SOLIDS ;  ACID
语种: 英语
WOS记录号: WOS:000290161900023
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115852
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Normal Univ, Sch Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Zhu, Yan-Yu,Sun, Zhen-Gang,Tong, Fei,et al. Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture[J]. DALTON TRANSACTIONS,2011,40(20):5584-5590.
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