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学科主题物理化学
Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture
Zhu, Yan-Yu1; Sun, Zhen-Gang1; Tong, Fei1; Liu, Zhong-Min2; Huang, Cui-Ying1; Wang, Wei-Nan1; Jiao, Cheng-Qi1; Wang, Cheng-Lin1; Li, Chao1; Chen, Kai1; Zhen-GangSun
刊名DALTON TRANSACTIONS
2011
ISSN待补充
DOI10.1039/c0dt01781g
40期:20页:5584-5590
收录类别SCI
文章类型Article
部门归属DNL12
项目归属DNL12
产权排名2,4
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]INITIO STRUCTURE DETERMINATION ; FRAMEWORKS MIL-N ; COORDINATION POLYMERS ; ORGANIC FRAMEWORKS ; MOLECULAR RECOGNITION ; VISIBLE LUMINESCENCE ; METAL PHOSPHONATES ; COMPLEXES ; SOLIDS ; ACID
英文摘要Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture; Eleven new lanthanide oxalatophosphonate hybrids with a 2D layered structures, namely, [Ln(H3L)(C2O4)]center dot 2H(2)O (Ln = La-Dy, Er and Y, H4L = C6H5CH2N(CH2PO3H2)(2)), have been synthesized under hydrothermal conditions and structurally characterized by X-ray single-crystal diffraction, X-ray powder diffraction, infrared spectroscopy, elemental analysis and thermogravimetric analysis. Compounds 1-11 are isomorphous and they exhibit a 2D framework structure. Two {LnO(8)} polyhedra and four {CPO3} tetrahedra are interconnected into a unit via corner-sharing, and the so-built units are bridged by the oxalate anions into a layer. The result of connections in this manner is the formation of a 24-atom window. The thermal stabilities and guest desorption-sorption properties of compounds 1-11 have been investigated. The luminescent properties of compounds 5, 6, 8 and 9 have also been studied.
语种英语
WOS记录号WOS:000290161900023
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/115852
专题中国科学院大连化学物理研究所
通讯作者Zhen-GangSun
作者单位1.Liaoning Normal Univ, Sch Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Zhu, Yan-Yu,Sun, Zhen-Gang,Tong, Fei,et al. Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture[J]. DALTON TRANSACTIONS,2011,40(20):5584-5590.
APA Zhu, Yan-Yu.,Sun, Zhen-Gang.,Tong, Fei.,Liu, Zhong-Min.,Huang, Cui-Ying.,...&Zhen-GangSun.(2011).Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture.DALTON TRANSACTIONS,40(20),5584-5590.
MLA Zhu, Yan-Yu,et al."Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture".DALTON TRANSACTIONS 40.20(2011):5584-5590.
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