DICP OpenIR
Subject Area物理化学
Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture
Zhu, Yan-Yu1; Sun, Zhen-Gang1; Tong, Fei1; Liu, Zhong-Min2; Huang, Cui-Ying1; Wang, Wei-Nan1; Jiao, Cheng-Qi1; Wang, Cheng-Lin1; Li, Chao1; Chen, Kai1; Zhen-GangSun
Source PublicationDALTON TRANSACTIONS
2011
ISSN待补充
DOI10.1039/c0dt01781g
Volume40Issue:20Pages:5584-5590
Indexed BySCI
SubtypeArticle
DepartmentDNL12
Funding ProjectDNL12
Contribution Rank2,4
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear
WOS Research AreaChemistry
WOS KeywordINITIO STRUCTURE DETERMINATION ; FRAMEWORKS MIL-N ; COORDINATION POLYMERS ; ORGANIC FRAMEWORKS ; MOLECULAR RECOGNITION ; VISIBLE LUMINESCENCE ; METAL PHOSPHONATES ; COMPLEXES ; SOLIDS ; ACID
AbstractHydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture; Eleven new lanthanide oxalatophosphonate hybrids with a 2D layered structures, namely, [Ln(H3L)(C2O4)]center dot 2H(2)O (Ln = La-Dy, Er and Y, H4L = C6H5CH2N(CH2PO3H2)(2)), have been synthesized under hydrothermal conditions and structurally characterized by X-ray single-crystal diffraction, X-ray powder diffraction, infrared spectroscopy, elemental analysis and thermogravimetric analysis. Compounds 1-11 are isomorphous and they exhibit a 2D framework structure. Two {LnO(8)} polyhedra and four {CPO3} tetrahedra are interconnected into a unit via corner-sharing, and the so-built units are bridged by the oxalate anions into a layer. The result of connections in this manner is the formation of a 24-atom window. The thermal stabilities and guest desorption-sorption properties of compounds 1-11 have been investigated. The luminescent properties of compounds 5, 6, 8 and 9 have also been studied.
Language英语
WOS IDWOS:000290161900023
Citation statistics
Cited Times:28[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/115852
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhen-GangSun
Affiliation1.Liaoning Normal Univ, Sch Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhu, Yan-Yu,Sun, Zhen-Gang,Tong, Fei,et al. Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture[J]. DALTON TRANSACTIONS,2011,40(20):5584-5590.
APA Zhu, Yan-Yu.,Sun, Zhen-Gang.,Tong, Fei.,Liu, Zhong-Min.,Huang, Cui-Ying.,...&Zhen-GangSun.(2011).Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture.DALTON TRANSACTIONS,40(20),5584-5590.
MLA Zhu, Yan-Yu,et al."Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture".DALTON TRANSACTIONS 40.20(2011):5584-5590.
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