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学科主题: 物理化学
题名: Highly Efficient and Modularly Tuned Bicyclic Organocatalyst for the Enantioselective Michael Addition of Aldehydes to Nitroalkenes
作者: Xiao, Jian1, 2;  Xu, Feng-Xia1;  Lu, Yun-Peng1;  Liu, Yan-Ling1;  Loh, Teck-Peng1
通讯作者: Teck-PengLoh
关键词: organocatalyst ;  bicyclic ;  enamine control ;  Michael addition
刊名: SYNTHESIS-STUTTGART
发表日期: 2011-06-01
DOI: 10.1055/s-0030-1260527
卷: 待补充, 期:12, 页:1912-1917
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 02T3
产权排名: 2,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
摘要: Highly Efficient and Modularly Tuned Bicyclic Organocatalyst for the Enantioselective Michael Addition of Aldehydes to Nitroalkenes
研究领域[WOS]: Chemistry
英文摘要: A new type of bicyclic organocatalyst has been successfully applied to the asymmetric Michael addition of aldehydes to nitrostyrenes in good yields and good enantioselectivities by using a self-assembly strategy. The success of this reaction is attributed to good control of the geometry of the enamine and efficient face shielding.
关键词[WOS]: BOND-FORMING REACTIONS ;  2,3-DISUBSTITUTED 4-NITROKETONES ;  ASYMMETRIC AMINOCATALYSIS ;  ALDOL REACTIONS ;  SILYL ETHERS ;  KETONES ;  ACTIVATION ;  CATALYSIS ;  FUNCTIONALIZATION ;  WATER
语种: 英语
WOS记录号: WOS:000291302900013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/115870
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Xiao, Jian,Xu, Feng-Xia,Lu, Yun-Peng,et al. Highly Efficient and Modularly Tuned Bicyclic Organocatalyst for the Enantioselective Michael Addition of Aldehydes to Nitroalkenes[J]. SYNTHESIS-STUTTGART,2011,待补充(12):1912-1917.
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