DICP OpenIR
Subject Area物理化学
Electrochemical preparation and characterization of PdPt nanocages with improved electrocatalytic activity toward oxygen reduction reaction
Zhang, Geng1,2; Shao, Zhi-Gang1; Lu, Wangting1,2; Xie, Feng1; Qin, Xiaoping1; Yi, Baolian1; Shao ZG(邵志刚)
KeywordCore-shell Fuel Cell Nanocage Oxygen Reduction Pdpt Nanoalloy
Source PublicationELECTROCHIMICA ACTA
2013-07-30
DOI10.1016/j.electacta.2013.04.045
Volume103Pages:66-76
Indexed BySCI
SubtypeArticle
DepartmentDNL03
Funding ProjectDNL0301
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectElectrochemistry
WOS Research AreaElectrochemistry
WOS KeywordCORE-SHELL NANOPARTICLES ; METHANOL OXIDATION ; PARTICLE-SIZE ; PT-ALLOY ; BIMETALLIC NANODENDRITES ; CATALYTIC-ACTIVITIES ; FUEL-CELLS ; PLATINUM ; NANOSTRUCTURES ; STABILITY
AbstractHollow PdPt nanocages were prepared by applying Potential cycling treatment on core shell Pd@Pt nanodendrites in 0.5 M sulfuric acid aqueous solutions, during which Pd core was dissolved and the Pd@Pt structure was transformed to hollow nanocages. The nanocages were comprised of bimetallic PdPt nanoalloys, which was confirmed by high-resolution TEM (HRTEM), scanning TEM-energy dispersive X-ray spectra (STEM-EDX), X-ray diffraction (XRD) and cyclic voltammetry (CV). The PdPt nanocages presented superior catalytic activity toward oxygen reduction reaction in comparison with Pd@Pt nanodendrites and commercial Pt/C catalysts owing to the alloying effect and special morphology. The nanocage morphology was still maintained after long-term durability testing, indicating good structure stability. (c) 2013 Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000321601100010
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/117679
Collection中国科学院大连化学物理研究所
Corresponding AuthorShao ZG(邵志刚)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Grp, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Geng,Shao, Zhi-Gang,Lu, Wangting,et al. Electrochemical preparation and characterization of PdPt nanocages with improved electrocatalytic activity toward oxygen reduction reaction[J]. ELECTROCHIMICA ACTA,2013,103:66-76.
APA Zhang, Geng.,Shao, Zhi-Gang.,Lu, Wangting.,Xie, Feng.,Qin, Xiaoping.,...&邵志刚.(2013).Electrochemical preparation and characterization of PdPt nanocages with improved electrocatalytic activity toward oxygen reduction reaction.ELECTROCHIMICA ACTA,103,66-76.
MLA Zhang, Geng,et al."Electrochemical preparation and characterization of PdPt nanocages with improved electrocatalytic activity toward oxygen reduction reaction".ELECTROCHIMICA ACTA 103(2013):66-76.
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