DICP OpenIR
Subject Area物理化学
Synergistic hydrogen generation from AlLi alloy and solid-state NaBH4 activated by CoCl2 in water for portable fuel cell
Fan, Mei-qiang1; Liu, Shu1; Sun, Li-Xian2; Xu, Fen3; Wang, Shuang2; Zhang, Jian2; Mei, De-sheng4; Huang, Fen-lei5; Zhang, Qing-ming5; Sun LX(孙立贤); Xu F(徐芬)
KeywordHydrogen Generation Alli Alloy Hydrolysis Mechanism Nabh4
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
2012-03-01
DOI10.1016/j.ijhydene.2011.06.040
Volume37Issue:5Pages:4571-4579
Indexed BySCI ; ISTP
SubtypeArticle
DepartmentDNL19
Funding ProjectDNL1903
Contribution Rank2,3
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels
WOS KeywordSODIUM-BOROHYDRIDE ; CATALYST ; ALUMINUM ; POWDERS ; METAL
AbstractSolid-state AlLi/NaBH4 mixture activated by CoCl2 salt is fabricated for hydrogen generation via a milling process, providing uniform dispersion of AlLi alloy and CoCl2 salt among pulverized NaBH4 particles in order to improve NaBH4 hydrolysis through the contact of NaBH4 with active catalytic sites. The active catalytic sites come from CO2B loaded in Al(OH)(3) (Bayerite) or LiAl2(OH)(7) hydrate, generated from the reaction of CoCl2, AlLi alloy, and NaBH4 in water. The results show that the gravimetric hydrogen storage capacity is as high as 6.4 wt.% and an efficiency of above 90% in 30-min hydrolysis at 323 K could be achieved using the limited amount of water. The hydrogen generation amount and rate could be regulated by changing the composition, mixing style, mixture/water weight ratio, and hydrolysis temperature. The relative mechanism is explored. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000301615200069
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/117749
Collection中国科学院大连化学物理研究所
Corresponding AuthorSun LX(孙立贤); Xu F(徐芬)
Affiliation1.China Jiliang Univ, Dept Mat Sci & Engn, Hangzhou 310018, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
3.Liaoning Normal Univ, Dept Chem Engn, Dalian 116029, Peoples R China
4.Chinese Acad Sci, Shanghai Inst Mat Med, Dept Med Chem, Shanghai 201203, Peoples R China
5.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
Recommended Citation
GB/T 7714
Fan, Mei-qiang,Liu, Shu,Sun, Li-Xian,et al. Synergistic hydrogen generation from AlLi alloy and solid-state NaBH4 activated by CoCl2 in water for portable fuel cell[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2012,37(5):4571-4579.
APA Fan, Mei-qiang.,Liu, Shu.,Sun, Li-Xian.,Xu, Fen.,Wang, Shuang.,...&徐芬.(2012).Synergistic hydrogen generation from AlLi alloy and solid-state NaBH4 activated by CoCl2 in water for portable fuel cell.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,37(5),4571-4579.
MLA Fan, Mei-qiang,et al."Synergistic hydrogen generation from AlLi alloy and solid-state NaBH4 activated by CoCl2 in water for portable fuel cell".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 37.5(2012):4571-4579.
Files in This Item:
File Name/Size DocType Version Access License
2012XMlCpcj0ym.PDF(1090KB) 开放获取--Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Fan, Mei-qiang]'s Articles
[Liu, Shu]'s Articles
[Sun, Li-Xian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Fan, Mei-qiang]'s Articles
[Liu, Shu]'s Articles
[Sun, Li-Xian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Fan, Mei-qiang]'s Articles
[Liu, Shu]'s Articles
[Sun, Li-Xian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.