DICP OpenIR
学科主题物理化学
Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties
Chua, Yong Shen1,2; Wu, Hui3,4; Zhou, Wei3,4; Udovic, Terrence J.3; Wu, Guotao1; Xiong, Zhitao1; Wong, Ming Wah2; Chen, Ping1; HuiWu; Wu GT(吴国涛)
刊名INORGANIC CHEMISTRY
2012-02-06
DOI10.1021/ic201898v
51期:3页:1599-1603
收录类别SCI
文章类型Article
部门归属DNL19
项目归属DNL1901
产权排名1, 1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]CRYSTAL-STRUCTURE ; AMMONIA-BORANE ; THERMAL-DECOMPOSITION ; METAL AMIDOBORANES ; RELEASE ; LITHIUM ; AMIDOTRIHYDROBORATE ; DEHYDROGENATION ; ALKALI ; NA
英文摘要The monoammoniate of calcium amidoborane, Ca(NH2BH3)(2)center dot NH3, was synthesized by ball milling an equimolar mixture of CaNH and AB. Its crystal structure has been determined and was found to contain a dihydrogen-bonded network. Thermal decomposition under an open-system begins with the evolution of about 1 equivalent/formula unit (equiv.) of NH3 at temperatures <100 degrees C followed by the decomposition of Ca(NH2BH3)(2) to release hydrogen. In a closed-system thermal decomposition process, hydrogen is liberated in two stages, at about 70 and 180 degrees C, with the first stage corresponding to an exothermic process. It has been found that the presence of the coordinated NH3 has induced the dehydrogenation to occur at low temperature. At the end of the dehydrogenation, about 6 equiv. (similar to 10.2 wt %) of hydrogen can be released, giving rise to the formation of CaB2N3H.
语种英语
WOS记录号WOS:000300474700052
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/117771
专题中国科学院大连化学物理研究所
通讯作者HuiWu; Wu GT(吴国涛)
作者单位1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore
3.NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA
4.Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA
推荐引用方式
GB/T 7714
Chua, Yong Shen,Wu, Hui,Zhou, Wei,et al. Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties[J]. INORGANIC CHEMISTRY,2012,51(3):1599-1603.
APA Chua, Yong Shen.,Wu, Hui.,Zhou, Wei.,Udovic, Terrence J..,Wu, Guotao.,...&吴国涛.(2012).Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties.INORGANIC CHEMISTRY,51(3),1599-1603.
MLA Chua, Yong Shen,et al."Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties".INORGANIC CHEMISTRY 51.3(2012):1599-1603.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2012WUP0qiBWGs.PDF(1086KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Chua, Yong Shen]的文章
[Wu, Hui]的文章
[Zhou, Wei]的文章
百度学术
百度学术中相似的文章
[Chua, Yong Shen]的文章
[Wu, Hui]的文章
[Zhou, Wei]的文章
必应学术
必应学术中相似的文章
[Chua, Yong Shen]的文章
[Wu, Hui]的文章
[Zhou, Wei]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。