DICP OpenIR
Subject Area物理化学
New chiral ferrocenyl P,S-ligands for highly diastereo- and enantioselective Ag(I)-catalyzed asymmetric [3+2] cycloaddition of azomethine ylides
Han, Mei-Ling1,2; Wang, Dao-Yong1; Zeng, Pei-Wei1; Zheng, Zhuo1; Hu, Xiang-Ping1; Hu XP(胡向平)
Source PublicationTETRAHEDRON-ASYMMETRY
2012-02-29
DOI10.1016/j.tetasy.2012.02.017
Volume23Issue:3-4Pages:306-312
Indexed BySCI ; IC ; CCR
SubtypeArticle
Department2
Funding Project02T2
Contribution Rank2,1
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
WOS Research AreaChemistry
WOS Keyword1,3-DIPOLAR CYCLOADDITION ; DIPHOSPHINE LIGANDS ; ALLYLIC ALKYLATIONS ; HYDROGENATION ; CATALYSIS ; DERIVATIVES ; REACTIVITY ; COMPLEX ; ENONES ; FAMILY
AbstractA new family of chiral ferrocenyl P,S-ligands incorporating an indole ring at the alpha-ferrocenylmethyl position has been prepared via a Friedel-Crafts alkylation reaction of (R-c,S-Fc)-PPFA with a variety of 2-indole thioethers. These newly developed ferrocenyl P,S-ligands proved to be efficient in the AgOAc-catalyzed asymmetric [3+2] cycloaddition of azomethine ylides with various dipolarophiles, giving cycloadducts with high diastereoselectivities and enantioselectivities (up to 99% ee). (C) 2012 Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000302973900018
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/117906
Collection中国科学院大连化学物理研究所
Corresponding AuthorHu XP(胡向平)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
Recommended Citation
GB/T 7714
Han, Mei-Ling,Wang, Dao-Yong,Zeng, Pei-Wei,et al. New chiral ferrocenyl P,S-ligands for highly diastereo- and enantioselective Ag(I)-catalyzed asymmetric [3+2] cycloaddition of azomethine ylides[J]. TETRAHEDRON-ASYMMETRY,2012,23(3-4):306-312.
APA Han, Mei-Ling,Wang, Dao-Yong,Zeng, Pei-Wei,Zheng, Zhuo,Hu, Xiang-Ping,&胡向平.(2012).New chiral ferrocenyl P,S-ligands for highly diastereo- and enantioselective Ag(I)-catalyzed asymmetric [3+2] cycloaddition of azomethine ylides.TETRAHEDRON-ASYMMETRY,23(3-4),306-312.
MLA Han, Mei-Ling,et al."New chiral ferrocenyl P,S-ligands for highly diastereo- and enantioselective Ag(I)-catalyzed asymmetric [3+2] cycloaddition of azomethine ylides".TETRAHEDRON-ASYMMETRY 23.3-4(2012):306-312.
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