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学科主题: 物理化学
题名: New chiral ferrocenyl P,S-ligands for highly diastereo- and enantioselective Ag(I)-catalyzed asymmetric [3+2] cycloaddition of azomethine ylides
作者: Han, Mei-Ling1, 2;  Wang, Dao-Yong1;  Zeng, Pei-Wei1;  Zheng, Zhuo1;  Hu, Xiang-Ping1
通讯作者: 胡向平
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2012-02-29
DOI: 10.1016/j.tetasy.2012.02.017
卷: 23, 期:3-4, 页:306-312
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 02T2
产权排名: 2,1
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: A new family of chiral ferrocenyl P,S-ligands incorporating an indole ring at the alpha-ferrocenylmethyl position has been prepared via a Friedel-Crafts alkylation reaction of (R-c,S-Fc)-PPFA with a variety of 2-indole thioethers. These newly developed ferrocenyl P,S-ligands proved to be efficient in the AgOAc-catalyzed asymmetric [3+2] cycloaddition of azomethine ylides with various dipolarophiles, giving cycloadducts with high diastereoselectivities and enantioselectivities (up to 99% ee). (C) 2012 Elsevier Ltd. All rights reserved.
关键词[WOS]: 1,3-DIPOLAR CYCLOADDITION ;  DIPHOSPHINE LIGANDS ;  ALLYLIC ALKYLATIONS ;  HYDROGENATION ;  CATALYSIS ;  DERIVATIVES ;  REACTIVITY ;  COMPLEX ;  ENONES ;  FAMILY
语种: 英语
WOS记录号: WOS:000302973900018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/117906
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China

Recommended Citation:
Han, Mei-Ling,Wang, Dao-Yong,Zeng, Pei-Wei,et al. New chiral ferrocenyl P,S-ligands for highly diastereo- and enantioselective Ag(I)-catalyzed asymmetric [3+2] cycloaddition of azomethine ylides[J]. TETRAHEDRON-ASYMMETRY,2012,23(3-4):306-312.
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