DICP OpenIR
Subject Area物理化学
The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials
Ma, Jiping1,2,3; Pang, Yi1; Wang, Min2,3; Xu, Jie2; Ma, Hong2; Nie, Xin2; Xu J(徐杰)
Source PublicationJOURNAL OF MATERIALS CHEMISTRY
2012
DOI10.1039/c2jm15457a
Volume22Issue:8Pages:3457-3461
Indexed BySCI
SubtypeArticle
DepartmentDNL06
Funding Project601
Contribution Rank2,1
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Materials Science
WOS KeywordAEROBIC OXIDATION ; COMONOMER REACTIVITY ; EFFICIENT ; GLYCEROL ; CATALYST ; 2,5-DIFORMYLFURAN ; HYDROGENOLYSIS ; DEHYDRATION ; POLYESTER ; CHEMICALS
AbstractFuran-based copolyesters were synthesized via polytransesterification of 2,5-furandicarboxylic acid (FDCA) with ethylene glycol (EG) and 1,4-butylene glycol (BG). The composition and thermal properties of the obtained copolyesters were characterized in detail by H-1 NMR and elemental analysis, differential scanning calorimeters (DSC) and thermogravimetric analysis (TGA). The H-1 NMR results showed that the ethylene segment content was consistently lower than that of butylene in the obtained copolyesters in comparison with the comonomer feeds. The reactivities of EG and BG with FDCA were intensively investigated. On the basis of kinetic studies, EG was found to be less reactive than BG. The thermal properties of the obtained copolyesters could be adjusted by variation of the EG/BG molar ratios in the copolyesters.
Language英语
WOS IDWOS:000299695400028
Citation statistics
Cited Times:122[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/117911
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu J(徐杰)
Affiliation1.Univ Akron, Dept Chem, Akron, OH 44325 USA
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Ma, Jiping,Pang, Yi,Wang, Min,et al. The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(8):3457-3461.
APA Ma, Jiping.,Pang, Yi.,Wang, Min.,Xu, Jie.,Ma, Hong.,...&徐杰.(2012).The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials.JOURNAL OF MATERIALS CHEMISTRY,22(8),3457-3461.
MLA Ma, Jiping,et al."The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials".JOURNAL OF MATERIALS CHEMISTRY 22.8(2012):3457-3461.
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