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学科主题: 物理化学
题名: Mesoporous cross-linked polymer copolymerized with chiral BINAP ligand coordinated to a ruthenium species as an efficient heterogeneous catalyst for asymmetric hydrogenation
作者: Sun, Qi1;  Meng, Xiangju1;  Liu, Xiao2;  Zhang, Xiaoming2;  Yang, Yan2;  Yang, Qihua2;  Xiao, Feng-Shou1
通讯作者: 杨启华 ;  肖丰收
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2012
DOI: 10.1039/c2cc35192g
卷: 48, 期:85, 页:10505-10507
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 5
项目归属: 506
产权排名: 2,3
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: We report here a successful preparation of a heterogeneous chiral catalyst from copolymerization of mesoporous cross-linked polymer with chiral BINAP ligands, followed by coordination of the BINAP with a ruthenium species, which exhibits high activity, excellent enantioselectivity, and extraordinary recyclability in asymmetric hydrogenation.
关键词[WOS]: MIYAURA COUPLING REACTION ;  POROUS ORGANIC POLYMERS ;  ENANTIOSELECTIVE HYDROGENATION ;  SUPPORTED CATALYSTS ;  NANOPOROUS POLYMER ;  RU CATALYSTS ;  FRAMEWORKS ;  SILICA ;  IMMOBILIZATION ;  OPPORTUNITIES
语种: 英语
WOS记录号: WOS:000309405300011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118008
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Zhejiang Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China
2.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Sun, Qi,Meng, Xiangju,Liu, Xiao,et al. Mesoporous cross-linked polymer copolymerized with chiral BINAP ligand coordinated to a ruthenium species as an efficient heterogeneous catalyst for asymmetric hydrogenation[J]. CHEMICAL COMMUNICATIONS,2012,48(85):10505-10507.
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