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学科主题: 物理化学
题名: Homogeneous palladium-catalyzed asymmetric hydrogenation
作者: Chen, Qing-An1;  Ye, Zhi-Shi1;  Duan, Ying1;  Zhou, Yong-Gui1
通讯作者: 周永贵
刊名: CHEMICAL SOCIETY REVIEWS
发表日期: 2013
DOI: 10.1039/c2cs35333d
卷: 42, 期:2, 页:497-511
收录类别: SCI
文章类型: Review
部门归属: 2
项目归属: 201
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The transition metal catalyzed asymmetric hydrogenation of unsaturated compounds arguably presents one of the most attractive methods for the synthesis of chiral compounds. Over the last few decades, Pd has gradually grown up as a new and popular metal catalyst in homogeneous asymmetric hydrogenation the same as traditional Ru, Rh and Ir catalysts. Much progress has been successfully achieved in the asymmetric reduction of imines, enamines, olefins, ketones and heteroarenes. It was also found that palladium catalyzed asymmetric hydrogenation could be used as a key step in tandem reactions to quickly synthesize chiral compounds. This tutorial review intends to offer an overview of recent progress in homogeneous palladium catalyzed asymmetric hydrogenation and should serve as an inspiration for further advances in this area.
关键词[WOS]: HIGHLY ENANTIOSELECTIVE SYNTHESIS ;  CONJUGATE REDUCTION ;  BRONSTED ACIDS ;  BOND FORMATION ;  FACILE ACCESS ;  C-N ;  KETONES ;  LIGANDS ;  DERIVATIVES ;  CHEMISTRY
语种: 英语
WOS记录号: WOS:000312460600007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118043
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Chen, Qing-An,Ye, Zhi-Shi,Duan, Ying,et al. Homogeneous palladium-catalyzed asymmetric hydrogenation[J]. CHEMICAL SOCIETY REVIEWS,2013,42(2):497-511.
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