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学科主题: 物理化学
题名: Rhodium(III)-catalyzed oxidative mono- and di-olefination of isonicotinamides
作者: Wei, Xiaohong1, 2;  Wang, Feng1;  Song, Guoyong1;  Du, Zhengyin2;  Li, Xingwei1
通讯作者: 李兴伟
刊名: ORGANIC & BIOMOLECULAR CHEMISTRY
发表日期: 2012
DOI: 10.1039/c2ob25773d
卷: 10, 期:29, 页:5521-5524
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 02T3
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: [RhCp*Cl-2](2) can catalyze the oxidative coupling of secondary isonicotinamides with activated olefins using Cu(OAc)(2) as an oxidant. The selectivity can be controlled by the solvent. In MeCN, the mono-olefination and two-fold oxidation reaction is the major pathway, while in THF this reaction gave mostly diolefination products. In both cases, the coupled products contain an exocyclic C=C bond.
关键词[WOS]: C-H BOND ;  STEREOSELECTIVE-SYNTHESIS ;  INTERNAL ALKYNES ;  ACID DERIVATIVES ;  BENZOIC-ACIDS ;  ACTIVATION ;  ALKENES ;  ARYLATION ;  CLEAVAGE ;  COUPLING/CYCLIZATION
语种: 英语
WOS记录号: WOS:000305965400005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118058
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.NW Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China

Recommended Citation:
Wei, Xiaohong,Wang, Feng,Song, Guoyong,et al. Rhodium(III)-catalyzed oxidative mono- and di-olefination of isonicotinamides[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2012,10(29):5521-5524.
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