DICP OpenIR
学科主题物理化学
Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose
Li, Guangyi1,2; Li, Ning1; Wang, Zhiqiang1,3; Li, Changzhi1; Wang, Aiqin1; Wang, Xiaodong1; Cong, Yu1; Zhang, Tao1; Zhang T(张涛)
关键词Renewable Resources Zirconium Heterogeneous Catalysis Platinum Biomass
刊名CHEMSUSCHEM
2012
DOI10.1002/cssc.201200228
5期:10页:1958-1966
收录类别SCI
文章类型Article
部门归属15
项目归属1501
产权排名1,1
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]MESOPOROUS SBA-15 SILICA ; HIGH-SURFACE-AREA ; CATALYTIC CONVERSION ; ALDOL-CONDENSATION ; LIQUID FUELS ; OXYGENATED HYDROCARBONS ; TRANSPORTATION FUELS ; GAMMA-VALEROLACTONE ; ETHYLENE-GLYCOL ; BOND FORMATION
英文摘要Hydroxyalkylationalkylation (HAA) coupled with hydrodeoxygenation is a promising route for the synthesis of renewable high-quality diesel or jet fuel. In this work, a series of solid-acid catalysts were firstly used for HAA between lignocellulose-derived furan and carbonyl compounds. Among the investigated catalysts, Nafion-212 resin demonstrated the highest activity and stability. Owing to the high activity of the reactants and the advantage in industrial integration, the HAA of 2-methylfuran (2-MF) and furfural can be considered as a prospective route in future applications. Catalyst loading, reaction temperature, and time had evident effects on the HAA of 2-MF and furfural over Nafion-212 resin. Finally, the HAA product of 2-MF and furfural was hydrogenated over a Pd/C catalyst and hydrodeoxygenated over Pt-loaded solid-acid catalysts. Pt/zirconium phosphate (Pt/ZrP) was found to be the best catalyst for hydrodeoxygenation. Over the 4?% Pt/ZrP catalyst, a 94?% carbon yield of diesel and 75?% carbon yield of C15 hydrocarbons (with 6-butylundecane as the major component) was achieved.
语种英语
WOS记录号WOS:000310074200012
引用统计
被引频次:90[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/118126
专题中国科学院大连化学物理研究所
通讯作者Zhang T(张涛)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China
3.Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China
推荐引用方式
GB/T 7714
Li, Guangyi,Li, Ning,Wang, Zhiqiang,et al. Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose[J]. CHEMSUSCHEM,2012,5(10):1958-1966.
APA Li, Guangyi.,Li, Ning.,Wang, Zhiqiang.,Li, Changzhi.,Wang, Aiqin.,...&张涛.(2012).Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose.CHEMSUSCHEM,5(10),1958-1966.
MLA Li, Guangyi,et al."Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose".CHEMSUSCHEM 5.10(2012):1958-1966.
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