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学科主题: 物理化学
题名: Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose
作者: Li, Guangyi1, 2;  Li, Ning1;  Wang, Zhiqiang1, 3;  Li, Changzhi1;  Wang, Aiqin1;  Wang, Xiaodong1;  Cong, Yu1;  Zhang, Tao1
通讯作者: 张涛
关键词: renewable resources ;  zirconium ;  heterogeneous catalysis ;  platinum ;  biomass
刊名: CHEMSUSCHEM
发表日期: 2012
DOI: 10.1002/cssc.201200228
卷: 5, 期:10, 页:1958-1966
收录类别: SCI
文章类型: Article
部门归属: 15
项目归属: 1501
产权排名: 1,1
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Hydroxyalkylationalkylation (HAA) coupled with hydrodeoxygenation is a promising route for the synthesis of renewable high-quality diesel or jet fuel. In this work, a series of solid-acid catalysts were firstly used for HAA between lignocellulose-derived furan and carbonyl compounds. Among the investigated catalysts, Nafion-212 resin demonstrated the highest activity and stability. Owing to the high activity of the reactants and the advantage in industrial integration, the HAA of 2-methylfuran (2-MF) and furfural can be considered as a prospective route in future applications. Catalyst loading, reaction temperature, and time had evident effects on the HAA of 2-MF and furfural over Nafion-212 resin. Finally, the HAA product of 2-MF and furfural was hydrogenated over a Pd/C catalyst and hydrodeoxygenated over Pt-loaded solid-acid catalysts. Pt/zirconium phosphate (Pt/ZrP) was found to be the best catalyst for hydrodeoxygenation. Over the 4?% Pt/ZrP catalyst, a 94?% carbon yield of diesel and 75?% carbon yield of C15 hydrocarbons (with 6-butylundecane as the major component) was achieved.
关键词[WOS]: MESOPOROUS SBA-15 SILICA ;  HIGH-SURFACE-AREA ;  CATALYTIC CONVERSION ;  ALDOL-CONDENSATION ;  LIQUID FUELS ;  OXYGENATED HYDROCARBONS ;  TRANSPORTATION FUELS ;  GAMMA-VALEROLACTONE ;  ETHYLENE-GLYCOL ;  BOND FORMATION
语种: 英语
WOS记录号: WOS:000310074200012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118126
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China
3.Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China

Recommended Citation:
Li, Guangyi,Li, Ning,Wang, Zhiqiang,et al. Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose[J]. CHEMSUSCHEM,2012,5(10):1958-1966.
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