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学科主题: 物理化学
题名: Direct oxidative phosphonylation of amines under metal-free conditions
作者: Wang, Haolong1;  Li, Xincheng1;  Wu, Fan1;  Wan, Boshun1
通讯作者: 万伯顺
关键词: Phosphonation ;  DDQ ;  Oxidative coupling ;  Tertiary amine
刊名: TETRAHEDRON LETTERS
发表日期: 2012-02-08
DOI: 10.1016/j.tetlet.2011.11.120
卷: 53, 期:6, 页:681-683
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 202
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Direct oxidation coupling of tertiary amines and dialkyl- or diphenyl-substituted phosphonates was developed. The reaction was mediated by DDQ under room temperature. Various phosphonates and N-aryl tetrahydroisoquinolines were tolerated in this reaction, and alpha-aminophosphonates were obtained with up to 99% yield. (C) 2011 Elsevier Ltd. All rights reserved.
关键词[WOS]: P BOND FORMATION ;  ENANTIOSELECTIVE HYDROPHOSPHONYLATION ;  BIOLOGICAL PROPERTIES ;  ACID-DERIVATIVES ;  PHOSPHONIC ACID ;  INHIBITORS ;  ANALOGS ;  IMINES ;  ESTERS ;  DDQ
语种: 英语
WOS记录号: WOS:000300527600019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118131
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Haolong,Li, Xincheng,Wu, Fan,et al. Direct oxidative phosphonylation of amines under metal-free conditions[J]. TETRAHEDRON LETTERS,2012,53(6):681-683.
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