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学科主题: 物理化学
题名: Iridium Catalyzed Asymmetric Hydrogenation of Cyclic Imines of Benzodiazepinones and Benzodiazepines
作者: Gao, Kai1;  Wu, Bo1;  Yu, Chang-Bin1;  Chen, Qing-An1;  Ye, Zhi-Shi1;  Zhou, Yong-Gui1
通讯作者: 周永贵
刊名: ORGANIC LETTERS
发表日期: 2012-08-03
DOI: 10.1021/ol301620z
卷: 14, 期:15, 页:3890-3893
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 201
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Highly enantioselective Ir-catalyzed hydrogenation of seven-membered cyclic imines of benzodiazepinones and benzodiazepines was achieved with up to 96% ee. This method provides a direct access to synthesize a range of chiral cyclic amines existing in numerous important natural products and clinical drugs.
关键词[WOS]: HIGHLY ENANTIOSELECTIVE HYDROGENATION ;  STEREOSELECTIVE-SYNTHESIS ;  HETEROAROMATIC-COMPOUNDS ;  DIPHOSPHINE LIGANDS ;  EFFICIENT SYNTHESIS ;  COMPLEXES ;  DERIVATIVES ;  ANTHRAMYCIN ;  TILIVALLINE ;  QUINOLINES
语种: 英语
WOS记录号: WOS:000307041600020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118187
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Gao, Kai,Wu, Bo,Yu, Chang-Bin,et al. Iridium Catalyzed Asymmetric Hydrogenation of Cyclic Imines of Benzodiazepinones and Benzodiazepines[J]. ORGANIC LETTERS,2012,14(15):3890-3893.
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