中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
学科主题: 物理化学
题名: Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature
作者: Zhang, Zehui1, 2;  Liu, Bing1, 2;  Zhao, Zongbao (Kent)3, 4
通讯作者: 张泽会
关键词: Fructose ;  Germanium(IV) chloride ;  Ionic liquids ;  Dehydration ;  5-Hydroxymethylfurfual
刊名: CARBOHYDRATE POLYMERS
发表日期: 2012-04-15
DOI: 10.1016/j.carbpol.2012.01.032
卷: 88, 期:3, 页:891-895
收录类别: SCI
文章类型: Article
部门归属: 18
项目归属: 1816
产权排名: 2,3
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic ;  Polymer Science
研究领域[WOS]: Chemistry ;  Polymer Science
英文摘要: Conversion of fructose into 5-hydroxymethylfurfural (HMF) catalyzed by Germanium(IV) chloride was studied in Dimethyl sulfoxide (DMSO) and [Bmim]Cl system at room temperature. The structure of ionic liquids and the ratio of ionic liquids to DMSO had a remarkable effect on this new catalytic system. The results indicated that 1-n-butyl-3-methylimidazolium chloride ([Bmim]Cl) was favorable for the dehydration of fructose to HMF. Under optimal conditions, a high HMF yield in 70% was obtained at 25 degrees C. In addition, it was also proved that there was a synergistic effect between the cation and anion of [Bmim]Cl on the dehydration of fructose to HMF by designed experiments. Finally, a possible mechanism for the dehydration of fructose to HMF was proposed. (C) 2012 Elsevier Ltd. All rights reserved.
关键词[WOS]: IONIC LIQUIDS ;  IMIDAZOLIUM CHLORIDE ;  CORN STOVER ;  BIOMASS ;  DEHYDRATION ;  CELLULOSE ;  SALTS ;  PRETREATMENT
语种: 英语
WOS记录号: WOS:000302196200012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118217
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2012fkbslfwbVz.PDF(495KB)----开放获取--View Download

作者单位: 1.S Cent Univ Nationalities, Coll Chem & Mat Sci, State Ethn Affairs Commiss, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China
2.S Cent Univ Nationalities, Coll Chem & Mat Sci, Minist Educ, Wuhan 430074, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

Recommended Citation:
Zhang, Zehui,Liu, Bing,Zhao, Zongbao . Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature[J]. CARBOHYDRATE POLYMERS,2012,88(3):891-895.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhang, Zehui]'s Articles
 [Liu, Bing]'s Articles
 [Zhao, Zongbao (Kent)]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhang, Zehui]‘s Articles
 [Liu, Bing]‘s Articles
 [Zhao, Zongbao (Kent)]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 2012fkbslfwbVz.PDF
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace