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学科主题物理化学
Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature
Zhang, Zehui1,2; Liu, Bing1,2; Zhao, Zongbao (Kent)3,4; Zhang ZH(张泽会)
关键词Fructose Germanium(Iv) Chloride Ionic Liquids Dehydration 5-hydroxymethylfurfual
刊名CARBOHYDRATE POLYMERS
2012-04-15
DOI10.1016/j.carbpol.2012.01.032
88期:3页:891-895
收录类别SCI
文章类型Article
部门归属18
项目归属1816
产权排名2,3
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Applied ; Chemistry, Organic ; Polymer Science
研究领域[WOS]Chemistry ; Polymer Science
关键词[WOS]IONIC LIQUIDS ; IMIDAZOLIUM CHLORIDE ; CORN STOVER ; BIOMASS ; DEHYDRATION ; CELLULOSE ; SALTS ; PRETREATMENT
英文摘要Conversion of fructose into 5-hydroxymethylfurfural (HMF) catalyzed by Germanium(IV) chloride was studied in Dimethyl sulfoxide (DMSO) and [Bmim]Cl system at room temperature. The structure of ionic liquids and the ratio of ionic liquids to DMSO had a remarkable effect on this new catalytic system. The results indicated that 1-n-butyl-3-methylimidazolium chloride ([Bmim]Cl) was favorable for the dehydration of fructose to HMF. Under optimal conditions, a high HMF yield in 70% was obtained at 25 degrees C. In addition, it was also proved that there was a synergistic effect between the cation and anion of [Bmim]Cl on the dehydration of fructose to HMF by designed experiments. Finally, a possible mechanism for the dehydration of fructose to HMF was proposed. (C) 2012 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000302196200012
引用统计
被引频次:51[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/118217
专题中国科学院大连化学物理研究所
通讯作者Zhang ZH(张泽会)
作者单位1.S Cent Univ Nationalities, Coll Chem & Mat Sci, State Ethn Affairs Commiss, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China
2.S Cent Univ Nationalities, Coll Chem & Mat Sci, Minist Educ, Wuhan 430074, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
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Zhang, Zehui,Liu, Bing,Zhao, Zongbao ,et al. Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature[J]. CARBOHYDRATE POLYMERS,2012,88(3):891-895.
APA Zhang, Zehui,Liu, Bing,Zhao, Zongbao ,&张泽会.(2012).Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature.CARBOHYDRATE POLYMERS,88(3),891-895.
MLA Zhang, Zehui,et al."Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature".CARBOHYDRATE POLYMERS 88.3(2012):891-895.
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