DICP OpenIR
Subject Area物理化学
Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature
Zhang, Zehui1,2; Liu, Bing1,2; Zhao, Zongbao (Kent)3,4; Zhang ZH(张泽会)
KeywordFructose Germanium(Iv) Chloride Ionic Liquids Dehydration 5-hydroxymethylfurfual
Source PublicationCARBOHYDRATE POLYMERS
2012-04-15
DOI10.1016/j.carbpol.2012.01.032
Volume88Issue:3Pages:891-895
Indexed BySCI
SubtypeArticle
Department18
Funding Project1816
Contribution Rank2,3
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Applied ; Chemistry, Organic ; Polymer Science
WOS Research AreaChemistry ; Polymer Science
WOS KeywordIONIC LIQUIDS ; IMIDAZOLIUM CHLORIDE ; CORN STOVER ; BIOMASS ; DEHYDRATION ; CELLULOSE ; SALTS ; PRETREATMENT
AbstractConversion of fructose into 5-hydroxymethylfurfural (HMF) catalyzed by Germanium(IV) chloride was studied in Dimethyl sulfoxide (DMSO) and [Bmim]Cl system at room temperature. The structure of ionic liquids and the ratio of ionic liquids to DMSO had a remarkable effect on this new catalytic system. The results indicated that 1-n-butyl-3-methylimidazolium chloride ([Bmim]Cl) was favorable for the dehydration of fructose to HMF. Under optimal conditions, a high HMF yield in 70% was obtained at 25 degrees C. In addition, it was also proved that there was a synergistic effect between the cation and anion of [Bmim]Cl on the dehydration of fructose to HMF by designed experiments. Finally, a possible mechanism for the dehydration of fructose to HMF was proposed. (C) 2012 Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000302196200012
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/118217
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang ZH(张泽会)
Affiliation1.S Cent Univ Nationalities, Coll Chem & Mat Sci, State Ethn Affairs Commiss, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China
2.S Cent Univ Nationalities, Coll Chem & Mat Sci, Minist Educ, Wuhan 430074, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Zehui,Liu, Bing,Zhao, Zongbao ,et al. Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature[J]. CARBOHYDRATE POLYMERS,2012,88(3):891-895.
APA Zhang, Zehui,Liu, Bing,Zhao, Zongbao ,&张泽会.(2012).Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature.CARBOHYDRATE POLYMERS,88(3),891-895.
MLA Zhang, Zehui,et al."Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature".CARBOHYDRATE POLYMERS 88.3(2012):891-895.
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