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学科主题: 物理化学
题名: Direct Oxidative C-P Bond Formation of Indoles with Dialkyl Phosphites
作者: Wang, Haolong1;  Li, Xincheng1;  Wu, Fan1;  Wan, Boshun1
通讯作者: 万伯顺
关键词: indole ;  dialkyl phosphite ;  phosphonation ;  silver acetate ;  oxidative coupling
刊名: SYNTHESIS-STUTTGART
发表日期: 2012-03-01
DOI: 10.1055/s-0031-1289700
卷: 44, 期:6, 页:941-945
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 202
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The direct phosphonation of indoles was developed. In this reaction, dialkyl phosphites and indoles were used as substrates, and the C-P bond was formed through oxidative coupling mediated by silver(I) acetate. Various indoles and different dialkyl phosphites were effective substrates for the reaction, and dialkylphosphoryl-substituted indoles were obtained in up to 71% yield.
关键词[WOS]: CROSS-COUPLING REACTIONS ;  PHOSPHORUS-CARBON BOND ;  AROMATIC-COMPOUNDS ;  ACIDS ;  PHOSPHONATION ;  PHOSPHONYLATION ;  DERIVATIVES ;  CYCLIZATION
语种: 英语
WOS记录号: WOS:000301344200015
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118242
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Haolong,Li, Xincheng,Wu, Fan,et al. Direct Oxidative C-P Bond Formation of Indoles with Dialkyl Phosphites[J]. SYNTHESIS-STUTTGART,2012,44(6):941-945.
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