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学科主题: 物理化学
题名: Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes
作者: Mao, Zhifeng1;  Wang, Zhe2;  Xu, Zhaoqing1, 2;  Huang, Fei1;  Yu, Zhengkun1;  Wang, Rui2
通讯作者: 许兆青 ;  余正坤 ;  RuiWang
刊名: ORGANIC LETTERS
发表日期: 2012-08-03
DOI: 10.1021/ol301517y
卷: 14, 期:15, 页:3854-3857
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 203
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Cu(OAc)(2)-mediated dehydrogenative cross-coupling between two heteroarenes has been realized in the absence of any other additive. A mechanism involving a formal Cu(II) to Cu(0) route by convergent disproportionation of the copper mediator is proposed and has been evidenced by copper mirror formation during the reaction. This synthetic protocol provides a concise and "green" access to unsymmetrical biheteroarenes bearing structural motifs of substantial utility in organic synthesis.
关键词[WOS]: C-H BONDS ;  COPPER-CATALYZED ARYLATION ;  GENERAL-METHOD ;  ARYL BROMIDES ;  SOLE OXIDANT ;  PALLADIUM ;  AZOLES ;  FUNCTIONALIZATIONS ;  HETEROCYCLES ;  ACIDS
语种: 英语
WOS记录号: WOS:000307041600011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118247
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Lanzhou Univ, Key Lab Preclin Study New Drugs Gansu Prov, Lanzhou 730000, Peoples R China

Recommended Citation:
Mao, Zhifeng,Wang, Zhe,Xu, Zhaoqing,et al. Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes[J]. ORGANIC LETTERS,2012,14(15):3854-3857.
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