DICP OpenIR
Subject Area物理化学
Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes
Mao, Zhifeng1; Wang, Zhe2; Xu, Zhaoqing1,2; Huang, Fei1; Yu, Zhengkun1; Wang, Rui2; Xu ZQ(许兆青); Yu ZK(余正坤); RuiWang
Source PublicationORGANIC LETTERS
2012-08-03
DOI10.1021/ol301517y
Volume14Issue:15Pages:3854-3857
Indexed BySCI ; IC ; CCR
SubtypeArticle
Department2
Funding Project203
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordC-H BONDS ; COPPER-CATALYZED ARYLATION ; GENERAL-METHOD ; ARYL BROMIDES ; SOLE OXIDANT ; PALLADIUM ; AZOLES ; FUNCTIONALIZATIONS ; HETEROCYCLES ; ACIDS
AbstractCu(OAc)(2)-mediated dehydrogenative cross-coupling between two heteroarenes has been realized in the absence of any other additive. A mechanism involving a formal Cu(II) to Cu(0) route by convergent disproportionation of the copper mediator is proposed and has been evidenced by copper mirror formation during the reaction. This synthetic protocol provides a concise and "green" access to unsymmetrical biheteroarenes bearing structural motifs of substantial utility in organic synthesis.
Language英语
WOS IDWOS:000307041600011
Citation statistics
Cited Times:68[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/118247
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu ZQ(许兆青); Yu ZK(余正坤); RuiWang
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Lanzhou Univ, Key Lab Preclin Study New Drugs Gansu Prov, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Mao, Zhifeng,Wang, Zhe,Xu, Zhaoqing,et al. Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes[J]. ORGANIC LETTERS,2012,14(15):3854-3857.
APA Mao, Zhifeng.,Wang, Zhe.,Xu, Zhaoqing.,Huang, Fei.,Yu, Zhengkun.,...&RuiWang.(2012).Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes.ORGANIC LETTERS,14(15),3854-3857.
MLA Mao, Zhifeng,et al."Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes".ORGANIC LETTERS 14.15(2012):3854-3857.
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