DICP OpenIR
学科主题物理化学
Catalytic Conversion of Inulin and Fructose into 5-Hydroxymethylfurfural by Lignosulfonic Acid in Ionic Liquids
Xie, Haibo1,2; Zhao, Zongbao K.1,2; Wang, Qian1; Xie HB(谢海波)
关键词Biomass Green Chemistry Ionic Liquids 5-hydroxymethylfurfural Lignosulfonic Acid
刊名CHEMSUSCHEM
2012
DOI10.1002/cssc.201100588
5期:5页:901-905
收录类别SCI
文章类型Article
部门归属18
项目归属1816
产权排名1,1
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]LIGNIN ; DEHYDRATION ; MEMBRANES ; EFFICIENT ; BIOMASS ; DESIGN
英文摘要In this work, we found that lignosulfonic acid (LS), which is a waste byproduct from the paper industry, in ionic liquids (ILs) can catalyze the dehydration of fructose and inulin into 5-hydroxymethylfurfural (HMF) efficiently, which is a promising potential substitute for petroleum-based building blocks. The effects of reaction time, temperature, catalyst loading, and reusability of the catalytic system were studied. It was found that a 94.3?% yield of HMF could be achieved in only 10 min at 100 degrees C under mild conditions. The reusability study of the LSIL catalytic system after removal of HMF by ethyl acetate extraction demonstrated that the catalytic activity decreased from 77.4 to 62.9?% after five cycles and the catalytic activity could be recovered after simply removing the accumulated humins by filtration after adding ethanol to the LSILs. The integrated utilization of a biorenewable feedstock, catalyst, and ILs is an example of an ideal green chemical process.
语种英语
WOS记录号WOS:000303854800012
引用统计
被引频次:52[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/118260
专题中国科学院大连化学物理研究所
通讯作者Xie HB(谢海波)
作者单位1.CAS, Dalian Inst Chem Phys, Dalian, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Xie, Haibo,Zhao, Zongbao K.,Wang, Qian,et al. Catalytic Conversion of Inulin and Fructose into 5-Hydroxymethylfurfural by Lignosulfonic Acid in Ionic Liquids[J]. CHEMSUSCHEM,2012,5(5):901-905.
APA Xie, Haibo,Zhao, Zongbao K.,Wang, Qian,&谢海波.(2012).Catalytic Conversion of Inulin and Fructose into 5-Hydroxymethylfurfural by Lignosulfonic Acid in Ionic Liquids.CHEMSUSCHEM,5(5),901-905.
MLA Xie, Haibo,et al."Catalytic Conversion of Inulin and Fructose into 5-Hydroxymethylfurfural by Lignosulfonic Acid in Ionic Liquids".CHEMSUSCHEM 5.5(2012):901-905.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2012DlIOZLCLDF.PDF(562KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Xie, Haibo]的文章
[Zhao, Zongbao K.]的文章
[Wang, Qian]的文章
百度学术
百度学术中相似的文章
[Xie, Haibo]的文章
[Zhao, Zongbao K.]的文章
[Wang, Qian]的文章
必应学术
必应学术中相似的文章
[Xie, Haibo]的文章
[Zhao, Zongbao K.]的文章
[Wang, Qian]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。