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学科主题: 物理化学
题名: Borohydride hydrazinates: high hydrogen content materials for hydrogen storage
作者: He, Teng1;  Wu, Hui2, 3;  Wu, Guotao1;  Wang, Junhu1;  Zhou, Wei2, 3;  Xiong, Zhitao1;  Chen, Juner1;  Zhang, Tao1;  Chen, Ping1
通讯作者: 陈萍
刊名: ENERGY & ENVIRONMENTAL SCIENCE
发表日期: 2012-02-01
DOI: 10.1039/c2ee03205h
卷: 5, 期:2, 页:5686-5689
收录类别: SCI
文章类型: Article
部门归属: DNL19;15
项目归属: DNL1901;1501
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Multidisciplinary ;  Energy & Fuels ;  Engineering, Chemical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Energy & Fuels ;  Engineering ;  Environmental Sciences & Ecology
英文摘要: A new class of hydrogen storage materials, borohydride hydrazinates, was successfully synthesized. In particular, the bidentate NH2NH2 coordinates with LiBH4 in molar ratios of 1 : 1 and 1 : 2 giving rise to a monoclinic LiBH4 center dot NH2NH2 and orthorhombic LiBH4 center dot 2NH(2)NH(2), respectively. Around 13.0 wt% H-2 can be released from LiBH4 center dot NH2NH2 at 140 degrees C in the presence of Fe-B catalysts.
关键词[WOS]: CRYSTAL-STRUCTURE ;  LITHIUM BOROHYDRIDE ;  AMMONIA-BORANE ;  CATALYTIC DECOMPOSITION ;  MAGNESIUM BOROHYDRIDE ;  NEUTRON-DIFFRACTION ;  METAL AMIDOBORANES ;  COMPLEX HYDRIDES ;  ALKALI ;  LIBH4
语种: 英语
WOS记录号: WOS:000299502300017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118308
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
2.Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA
3.Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA

Recommended Citation:
He, Teng,Wu, Hui,Wu, Guotao,et al. Borohydride hydrazinates: high hydrogen content materials for hydrogen storage[J]. ENERGY & ENVIRONMENTAL SCIENCE,2012,5(2):5686-5689.
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