DICP OpenIR
Subject Area物理化学
Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines
Hou, Chuan-Jin1,2; Wang, Ya-Hui1; Zheng, Zhuo1; Xu, Jie1; Hu, Xiang-Ping1; Hu XP(胡向平)
Source PublicationORGANIC LETTERS
2012-07-06
DOI10.1021/ol301618r
Volume14Issue:13Pages:3554-3557
Indexed BySCI ; IC ; CCR
SubtypeArticle
Department2;DNL06
Funding Project02T2;DNL0601
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordENANTIOSELECTIVE HYDROGENATION ; IMINES ; HYDROFORMYLATION ; COMPLEXES ; QUINAPHOS ; DERIVATIVES
AbstractA mild and general iridium-catalyzed, highly enantioselective hydrogenation of sterically hindered N-arylimines with a new H-8-BINOL-derived phosphine-phosphoramidite ligand has been developed. The present catalytic system features high turnover numbers (up to 100000) and good to perfect enantioselectivities (up to 99% ee) for the hydrogenation of a variety of sterically hindered N-arylimines.
Language英语
WOS IDWOS:000306050300081
Citation statistics
Cited Times:23[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/118313
Collection中国科学院大连化学物理研究所
Corresponding AuthorHu XP(胡向平)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
Recommended Citation
GB/T 7714
Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,et al. Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines[J]. ORGANIC LETTERS,2012,14(13):3554-3557.
APA Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,Xu, Jie,Hu, Xiang-Ping,&胡向平.(2012).Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines.ORGANIC LETTERS,14(13),3554-3557.
MLA Hou, Chuan-Jin,et al."Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines".ORGANIC LETTERS 14.13(2012):3554-3557.
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