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学科主题物理化学
Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines
Hou, Chuan-Jin1,2; Wang, Ya-Hui1; Zheng, Zhuo1; Xu, Jie1; Hu, Xiang-Ping1; Hu XP(胡向平)
刊名ORGANIC LETTERS
2012-07-06
DOI10.1021/ol301618r
14期:13页:3554-3557
收录类别SCI ; IC ; CCR
文章类型Article
部门归属2;DNL06
项目归属02T2;DNL0601
产权排名1,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ENANTIOSELECTIVE HYDROGENATION ; IMINES ; HYDROFORMYLATION ; COMPLEXES ; QUINAPHOS ; DERIVATIVES
英文摘要A mild and general iridium-catalyzed, highly enantioselective hydrogenation of sterically hindered N-arylimines with a new H-8-BINOL-derived phosphine-phosphoramidite ligand has been developed. The present catalytic system features high turnover numbers (up to 100000) and good to perfect enantioselectivities (up to 99% ee) for the hydrogenation of a variety of sterically hindered N-arylimines.
语种英语
WOS记录号WOS:000306050300081
引用统计
被引频次:22[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/118313
专题中国科学院大连化学物理研究所
通讯作者Hu XP(胡向平)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
推荐引用方式
GB/T 7714
Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,et al. Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines[J]. ORGANIC LETTERS,2012,14(13):3554-3557.
APA Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,Xu, Jie,Hu, Xiang-Ping,&胡向平.(2012).Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines.ORGANIC LETTERS,14(13),3554-3557.
MLA Hou, Chuan-Jin,et al."Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines".ORGANIC LETTERS 14.13(2012):3554-3557.
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