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学科主题: 物理化学
题名: Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines
作者: Hou, Chuan-Jin1, 2;  Wang, Ya-Hui1;  Zheng, Zhuo1;  Xu, Jie1;  Hu, Xiang-Ping1
通讯作者: 胡向平
刊名: ORGANIC LETTERS
发表日期: 2012-07-06
DOI: 10.1021/ol301618r
卷: 14, 期:13, 页:3554-3557
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2;DNL06
项目归属: 02T2;DNL0601
产权排名: 1,1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A mild and general iridium-catalyzed, highly enantioselective hydrogenation of sterically hindered N-arylimines with a new H-8-BINOL-derived phosphine-phosphoramidite ligand has been developed. The present catalytic system features high turnover numbers (up to 100000) and good to perfect enantioselectivities (up to 99% ee) for the hydrogenation of a variety of sterically hindered N-arylimines.
关键词[WOS]: ENANTIOSELECTIVE HYDROGENATION ;  IMINES ;  HYDROFORMYLATION ;  COMPLEXES ;  QUINAPHOS ;  DERIVATIVES
语种: 英语
WOS记录号: WOS:000306050300081
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118313
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China

Recommended Citation:
Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,et al. Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines[J]. ORGANIC LETTERS,2012,14(13):3554-3557.
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