DICP OpenIR
Subject Area物理化学
Recent Advances in Preferential Oxidation of CO Reaction over Platinum Group Metal Catalysts
Liu, Kuo; Wang, Aiqin; Zhang, Tao; Zhang T(张涛)
KeywordPlatinum Group Metal Catalysts Prox Activity Mechanism O-2 Activation Oh Groups
Source PublicationACS CATALYSIS
2012-06-01
DOI10.1021/cs200418w
Volume2Issue:6Pages:1165-1178
Indexed BySCI
SubtypeReview
Department15
Funding Project1501
Contribution Rank1,1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordHYDROGEN-RICH STREAM ; FUEL-CELL APPLICATIONS ; WATER-GAS-SHIFT ; CARBON-MONOXIDE OXIDATION ; TEMPERATURE PROX REACTION ; SUPPORTED GOLD CATALYSTS ; PT-FE/ZEOLITE CATALYSTS ; RHODIUM-BASED CATALYSTS ; EXCESS H-2 CONDITIONS ; SELECTIVE OXIDATION
AbstractPreferential oxidation of CO (PROX) is an important reaction for removing small amounts of CO to a parts-per-million level from the hydrogen-rich stream, which will be ultimately supplied as a fuel to polymer electrolyte membrane fuel cells. The key to the application of PROX is to develop a highly active and selective catalyst that operates well in a wide temperature window (e.g., 80-180 degrees C) and has good resistance to CO2 and steam. In the past decades, various catalyst formulations have been developed, among which platinum group metal catalysts, including Pt, Ru, and Ir-in particular, those modified with promoters such as alkali metals and reducible metal oxides-have received a great deal of attention for their significantly improved catalytic activities in the low-temperature range. In this minireview, the recent advances of the platinum group metal catalysts for the PROX reaction are summarized, including performances of unpromoted and promoted catalysts, reaction mechanisms, and kinetics. In addition, the important roles of hydroxyl groups in discussed.
Language英语
WOS IDWOS:000304682600030
Citation statistics
Cited Times:200[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/118340
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang T(张涛)
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, Kuo,Wang, Aiqin,Zhang, Tao,et al. Recent Advances in Preferential Oxidation of CO Reaction over Platinum Group Metal Catalysts[J]. ACS CATALYSIS,2012,2(6):1165-1178.
APA Liu, Kuo,Wang, Aiqin,Zhang, Tao,&张涛.(2012).Recent Advances in Preferential Oxidation of CO Reaction over Platinum Group Metal Catalysts.ACS CATALYSIS,2(6),1165-1178.
MLA Liu, Kuo,et al."Recent Advances in Preferential Oxidation of CO Reaction over Platinum Group Metal Catalysts".ACS CATALYSIS 2.6(2012):1165-1178.
Files in This Item:
File Name/Size DocType Version Access License
20128yJ0UZeyy7.PDF(323KB) 开放获取--Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Kuo]'s Articles
[Wang, Aiqin]'s Articles
[Zhang, Tao]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Kuo]'s Articles
[Wang, Aiqin]'s Articles
[Zhang, Tao]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Kuo]'s Articles
[Wang, Aiqin]'s Articles
[Zhang, Tao]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.