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学科主题物理化学
Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-L-phenylalanine (C14H19NO4)
Zhao, Z. -M.3; Sun, L. -X.3; Tan, Z. -C.1,2; Tan ZC(谭志诚)
关键词Heat Capacity Thermodynamic Property N-(Tert-butoxycarbonyl)-l-phenylalanine
刊名JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2012-03-01
DOI10.1007/s10973-011-1610-x
107期:3页:1315-1319
收录类别SCI
文章类型Article
部门归属DNL19
项目归属DNL1903
产权排名1,1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ADIABATIC CALORIMETER ; SMALL SAMPLES
英文摘要The heat capacities of N-(tert-butoxycarbonyl)-L- phenylalanine (abbreviated to NTBLP in this article), as an important chemical intermediates used to synthesize proteins and polypeptides, were measured by means of a fully automated adiabatic calorimeter over the temperature range from 78 to 350 K. The measured experimental heat capacities were fitted to a polynomial equation as a function of temperature. The thermodynamic functions, H-T - H-298.15K and S-T - S-298.15K, were calculated based on the heat capacity polynomial equation in the temperature range of (80-350 K) with an interval of 5 K. The thermal stability of the compound was further studied using TG and DSC analyses; a possible mechanism for thermal decomposition of the compound was suggested.
语种英语
WOS记录号WOS:000302703400058
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/118377
专题中国科学院大连化学物理研究所
通讯作者Tan ZC(谭志诚)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
3.Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Z. -M.,Sun, L. -X.,Tan, Z. -C.,et al. Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-L-phenylalanine (C14H19NO4)[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2012,107(3):1315-1319.
APA Zhao, Z. -M.,Sun, L. -X.,Tan, Z. -C.,&谭志诚.(2012).Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-L-phenylalanine (C14H19NO4).JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,107(3),1315-1319.
MLA Zhao, Z. -M.,et al."Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-L-phenylalanine (C14H19NO4)".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 107.3(2012):1315-1319.
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