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学科主题: 物理化学
题名: Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents
作者: Tan, Dazhi1;  Fan, Wenjie2;  Xiong, Wannan1;  Sun, Hanxue3;  Cheng, Yaqi1;  Liu, Xiaoyu1;  Meng, Changgong1;  Li, An3;  Deng, Wei-Qiao2
通讯作者: ChanggongMeng ;  AnLi ;  邓伟侨
关键词: conjugated polymers ;  morphology ;  networks ;  organic solvents storage ;  two dimension
刊名: MACROMOLECULAR CHEMISTRY AND PHYSICS
发表日期: 2012-07-26
DOI: 10.1002/macp.201200084
卷: 213, 期:14, 页:1435-1440
收录类别: SCI
文章类型: Article
部门归属: 11
项目归属: 11T4
产权排名: 2,2
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Polymer Science
研究领域[WOS]: Polymer Science
英文摘要: Two-dimensional conjugated microporous polymers (CMPs) composed of alternative phenylene and ethynylene units are synthesized, by cross-coupling polymerization of 1,3,5-triethynylbenzene and 1,3,5-tribromobenzene with various solvents. Our work shows that the morphology of CMPs is greatly affected by the choice of solvents used in synthesis. Sphere, tubular, and plate-like structures are received by using the toluene, p-xylene, and mesitylene solvents, respectively. Our results demonstrate that the morphology of CMPs affects the storage capacity for organic solvents remarkably, with the plate-like CMP showing best performance. This work is expected to provide useful guidance to rationally design CMPs as absorbent materials for organic solvents.
关键词[WOS]: TRIAZINE-BASED FRAMEWORKS ;  SURFACE-AREA ;  INTRINSIC MICROPOROSITY ;  NETWORKS ;  MACROCYCLES ;  POROSITY ;  FILMS
语种: 英语
WOS记录号: WOS:000306406100003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118416
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Univ Technol, Expt Ctr Chem, Fac Chem Environm & Biol Sci & Technol, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
3.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China

Recommended Citation:
Tan, Dazhi,Fan, Wenjie,Xiong, Wannan,et al. Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2012,213(14):1435-1440.
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