DICP OpenIR
Subject Area物理化学
Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents
Tan, Dazhi1; Fan, Wenjie2; Xiong, Wannan1; Sun, Hanxue3; Cheng, Yaqi1; Liu, Xiaoyu1; Meng, Changgong1; Li, An3; Deng, Wei-Qiao2; ChanggongMeng; AnLi; Deng WQ(邓伟侨)
KeywordConjugated Polymers Morphology Networks Organic Solvents Storage Two Dimension
Source PublicationMACROMOLECULAR CHEMISTRY AND PHYSICS
2012-07-26
ISSN1022-1352
DOI10.1002/macp.201200084
Volume213Issue:14Pages:1435-1440
Indexed BySCI
SubtypeArticle
Department11
Funding Project11T4
Contribution Rank2,2
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPolymer Science
WOS Research AreaPolymer Science
WOS KeywordTRIAZINE-BASED FRAMEWORKS ; SURFACE-AREA ; INTRINSIC MICROPOROSITY ; NETWORKS ; MACROCYCLES ; POROSITY ; FILMS
AbstractTwo-dimensional conjugated microporous polymers (CMPs) composed of alternative phenylene and ethynylene units are synthesized, by cross-coupling polymerization of 1,3,5-triethynylbenzene and 1,3,5-tribromobenzene with various solvents. Our work shows that the morphology of CMPs is greatly affected by the choice of solvents used in synthesis. Sphere, tubular, and plate-like structures are received by using the toluene, p-xylene, and mesitylene solvents, respectively. Our results demonstrate that the morphology of CMPs affects the storage capacity for organic solvents remarkably, with the plate-like CMP showing best performance. This work is expected to provide useful guidance to rationally design CMPs as absorbent materials for organic solvents.
Language英语
WOS IDWOS:000306406100003
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/118416
Collection中国科学院大连化学物理研究所
Corresponding AuthorChanggongMeng; AnLi; Deng WQ(邓伟侨)
Affiliation1.Dalian Univ Technol, Expt Ctr Chem, Fac Chem Environm & Biol Sci & Technol, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
3.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
Recommended Citation
GB/T 7714
Tan, Dazhi,Fan, Wenjie,Xiong, Wannan,et al. Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2012,213(14):1435-1440.
APA Tan, Dazhi.,Fan, Wenjie.,Xiong, Wannan.,Sun, Hanxue.,Cheng, Yaqi.,...&邓伟侨.(2012).Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents.MACROMOLECULAR CHEMISTRY AND PHYSICS,213(14),1435-1440.
MLA Tan, Dazhi,et al."Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents".MACROMOLECULAR CHEMISTRY AND PHYSICS 213.14(2012):1435-1440.
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