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学科主题: 物理化学
题名: Asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acid derivatives via Rh-catalyzed asymmetric hydrogenation
作者: Luo, Li-Bin1;  Wang, Dao-Yong2;  Zhou, Xiao-Mao1;  Zheng, Zhuo1, 2;  Hu, Xiang-Ping2
通讯作者: 周小毛 ;  胡向平
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2011-12-31
DOI: 10.1016/j.tetasy.2011.12.002
卷: 22, 期:24, 页:2117-2123
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 2
项目归属: 02T2
产权排名: 2,2
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The commercially available ferrocene-based diphosphine ligand (S-c,S-Fc)-TaniaPhos was found to be highly effective in the Rh-catalyzed asymmetric hydrogenation of 3-aryl-2-(phosphonomethyl)propenates. Excellent enantioselectivity (90-98% ee) and high catalytic activity (S/C up to 1000) have been achieved, which represents the best results reported so far. (C) 2011 Elsevier Ltd. All rights reserved.
关键词[WOS]: GLUTAMYL-GAMMA-GLUTAMATE ;  POTENT INHIBITORS ;  ENANTIOSELECTIVE HYDROGENATION ;  SELECTIVE INHIBITORS ;  ITACONIC ACID ;  SYNTHETASE ;  LIGANDS ;  ANALOGS ;  LEADS
语种: 英语
WOS记录号: WOS:000301892700008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/118571
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Hunan Agr Univ, Inst Pesticide, Changsha 410128, Hunan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Luo, Li-Bin,Wang, Dao-Yong,Zhou, Xiao-Mao,et al. Asymmetric synthesis of 2-alkyl-3-phosphonopropanoic acid derivatives via Rh-catalyzed asymmetric hydrogenation[J]. TETRAHEDRON-ASYMMETRY,2011,22(24):2117-2123.
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